. 2021 Jul 21;13(8):507. doi: 10.3390/toxins13080507

Table 4.

Analytical parameters of the method for determination of mycotoxins in milk.

Mycotoxin	RT (min.)	Mass (g/mol)	Molecularion	Transition (m/z)	Calibration Range (ng/L)	LOD (ng/L)	LOQ (ng/L)
AFM₁	4.09	328.3	[M+H]⁺	329.0 > 273.1 ^a	31–500	5	15
				329.0 > 229.0 ^b
AFB₁	4.80	312.3	[M+H]⁺	312.7 > 284.9 ^a	31–500	40	120
				312.7 > 241.1 ^b
AFB₂	4.59	314.3	[M+H]⁺	314.7 > 259.0 ^a	31–500	40	120
				314.7 > 287.0 ^b
AFG₁	4.46	328.3	[M+H]⁺	328.9 > 243.0 ^a	63–1000	40	120
				328.9 > 199.5 ^b
AFG₂	4.18	330.3	[M+H]⁺	330.9 > 245.0 ^a	94–1500	60	180
				330.9 > 188.9 ^b
DON	2.04	296.3	[M+H]⁺	297.3 > 249.1 ^a	313–5000	333	1223
				297.3 > 231.1 ^b
DOM-1	2.62	282.1	[M+Ac]⁻	339.2 > 249.1 ^a	625–10,000	170	310
				339.2 > 59.1 ^b
OTA	5.70	403.1	[M+H]⁺	404.0 > 238.9 ^a	63–1000	5	17
				404.0 > 357.9 ^b
FB₁	5.34	721.8	[M+H]⁺	722.5 > 334.0 ^a	625–10,000	300	620
				722.5 > 352.1 ^b
FB₂	5.74	705.8	[M+H]⁺	706.5 > 336.2 ^a	625–10,000	100	330
				706.5 > 318.3 ^b
ZEN	6.01	318.1	[M−H]⁻	317.1 > 175.1 ^a	313–5000	100	300
				317.1 > 130.9 ^b
α-ZEL	5.53	320.2	[M–H]⁻	319.1 > 275.2 ^a	313–5000	73	283
				319.1 > 160.2 ^b
β-ZEL	5.76	320.2	[M–H]⁻	319.1 > 275.2 ^a	313–5000	60	200
				319.1 > 160.2 ^b

RT: Retention time; LOD: Limit of detection; LOQ: Limit of quantification; AF: aflatoxin; DON: deoxynivalenol; DOM-1: de-epoxy-deoxynivalenol; OTA: ochratoxin A; FB: fumonisin; ZEN: zearalenone; α-ZEL: α-zearalenol; β-ZEL: β-zearalenol. ^a Transitions used in the quantification. ^b Transitions used in the confirmation.