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. 2021 Jul 25;77(Pt 4):638–648. doi: 10.1107/S2052520621006715

Table 1. Experimental details.

  YCdMg 1/1-cAP YCdMg 2/1-cAP
Crystal data
Chemical formula Y24Cd109.89Mg35.29 Y90.40Cd432.91Mg177.41
M r 15344.63 61013.94
Crystal system, space group Cubic, I m\overline{3} Cubic, P a\overline{3}
Temperature (K) 100 298
a (Å) 15.4577 (1) 25.0654 (1)
V3) 3693.47 (3) 15747.9 (1)
Z 1 1
F(000) 6660 26441
D x (Mg m−3) 6.899 6.434
Radiation type Mo Kα Mo Kα
μ (mm−1) 25.01 22.54
Crystal size (mm) 0.08 × 0.08 × 0.07 0.65 × 0.60 × 0.50
 
Data collection
Diffractometer MicroMax007HF - Saturn 724 HG XtaLAB Synergy R, HyPix
Absorption correction Multi-scan (CrysAlis PRO). Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm. Multi-scan (CrysAlis PRO). Empirical absorption correction using spherical harmonics, implemented in SCALE3 ABSPACK scaling algorithm.
T min, T max 0.505, 1.000 0.766, 1.000
No. of measured, independent and observed [I > 2σ(I)] reflections 64 031, 2579, 2562 422 818, 5382, 5128
R int 0.029 0.037
(sin θ/λ)max−1) 0.976 0.625
 
Refinement
Refinement composition Y14.18Cd64.95Mg20.86 Y12.71Cd60.47Mg26.82
R[F 2 > 2σ(F 2)], wR(F 2), S 0.022, 0.051, 1.25 0.038, 0.091, 1.17
No. of reflections 2579 5382
No. of parameters 76 438
No. of restraints 0 6
Δρmax, Δρmin (e Å−3) 2.37, −1.36 1.84, −1.36

Computer programs: CrysAlis PRO 1.171.39.46 (Rigaku Oxford Diffraction, 2018), SUPERFLIP (Palatinus & Chapuis, 2007), SHELXL2016/6 (Sheldrick, 2015).