Table 1.
Quantitative determination (mg/g) of 53 phytochemicals in methanol and ethanol extracts of Anamur banana
| No | Compounds | RTa | Mother Ion (m/z) | Fragment Ions | Ion Mode | Amounts (mg/g) | |
|---|---|---|---|---|---|---|---|
| Methanol | Ethanol | ||||||
| 1 | Quinic acid | 3.0 | 190.8 | 93.0 | Neg | 6.51 ± 0.002 | 4.54 ± 0.001 |
| 2 | Fumaric aid | 3.9 | 115.2 | 40.9 | Neg | – | – |
| 3 | Aconitic acid | 4.0 | 172.8 | 129.0 | Neg | 0.23 ± 0.000 | 0.008 ± 0.000 |
| 4 | Gallic acid | 4.4 | 168.8 | 79.0 | Neg | – | – |
| 5 | Epigallocatechin | 6.7 | 304.8 | 219.0 | Neg | – | – |
| 6 | Protocatechuic acid | 6.8 | 152.8 | 108.0 | Neg | – | – |
| 7 | Catechin | 7.4 | 288.8 | 203.1 | Neg | – | – |
| 8 | Gentisic acid | 8.3 | 152.8 | 109.0 | Neg | – | – |
| 9 | Chlorogenic acid | 8.4 | 353.0 | 85.0 | Neg | – | – |
| 10 | Protocatechuic aldehyde | 8.5 | 137.2 | 92.0 | Neg | – | – |
| 11 | Tannic acid | 9.2 | 182.8 | 78.0 | Neg | – | – |
| 12 | Epigallocatechingallate | 9.4 | 457.0 | 305.1 | Neg | – | – |
| 13 | 1,5–dicaffeoylquinic acid | 9.8 | 515.0 | 191.0 | Neg | – | – |
| 14 | 4–OH Benzoic acid | 10.5 | 137.2 | 65.0 | Neg | – | – |
| 15 | Epicatechin | 11.6 | 289.0 | 203.0 | Neg | – | – |
| 16 | Vanilic acid | 11.8 | 166.8 | 108.0 | Neg | – | – |
| 17 | Caffeic acid | 12.1 | 179.0 | 134.0 | Neg | – | – |
| 18 | Syringic acid | 12.6 | 196.8 | 166.9 | Neg | – | – |
| 19 | Vanillin | 13.9 | 153.1 | 125.0 | Poz | – | – |
| 20 | Syringic aldehyde | 14.6 | 181.0 | 151.1 | Neg | – | – |
| 21 | Daidzin | 15.2 | 417.1 | 199.0 | Poz | – | – |
| 22 | Epicatechingallate | 15.5 | 441.0 | 289.0 | Neg | – | – |
| 23 | Piceid | 17.2 | 391.0 | 135/106.9 | Poz | – | – |
| 24 | p–Coumaric acid | 17.8 | 163.0 | 93.0 | Neg | – | – |
| 25 | Ferulic acid–D3–ISh | 18.8 | 196.2 | 152.1 | Neg | – | – |
| 26 | Ferulic acid | 18.8 | 192.8 | 149.0 | Neg | – | – |
| 27 | Sinapic acid | 18.9 | 222.8 | 193.0 | Neg | – | – |
| 28 | Coumarin | 20.9 | 146.9 | 103.1 | Poz | – | – |
| 29 | Salicylic acid | 21.8 | 137.2 | 65.0 | Neg | – | – |
| 30 | Cynaroside | 23.7 | 447.0 | 284.0 | Neg | – | – |
| 31 | Miquelianin | 24.1 | 477.0 | 150.9 | Neg | – | – |
| 32 | Rutin-D3-ISh | 25.5 | 612.2 | 304.1 | Neg | – | – |
| 33 | Rutin | 25.6 | 608.9 | 301.0 | Neg | – | – |
| 34 | isoquercitrin | 25.6 | 463.0 | 271.0 | Neg | – | – |
| 35 | Hesperidin | 25.8 | 611.2 | 449.0 | Poz | 0.015 ± 0.000 | – |
| 36 | o-Coumaric acid | 26.1 | 162.8 | 93.0 | Neg | – | – |
| 37 | Genistin | 26.3 | 431.0 | 239.0 | Neg | – | – |
| 38 | Rosmarinic acid | 26.6 | 359.0 | 197.0 | Neg | – | – |
| 39 | Ellagic acid | 27.6 | 301.0 | 284.0 | Neg | – | – |
| 40 | Cosmosiin | 28.2 | 431.0 | 269.0 | Neg | – | – |
| 41 | Quercitrin | 29.8 | 447.0 | 301.0 | Neg | – | – |
| 42 | Astragalin | 30.4 | 447.0 | 255.0 | Neg | – | – |
| 43 | Nicotiflorin | 30.6 | 592.9 | 255.0/284.0 | Neg | – | – |
| 44 | Fisetin | 30.6 | 285.0 | 163.0 | Neg | – | – |
| 45 | Daidzein | 34.0 | 253.0 | 223.0 | Neg | – | – |
| 46 | Quercetin-D3-ISh | 35.6 | 304.0 | 275.9 | Neg | – | – |
| 47 | Quercetin | 35.7 | 301.0 | 272.9 | Neg | – | – |
| 48 | Naringenin | 35.9 | 270.9 | 119.0 | Neg | – | – |
| 49 | Hesperetin | 36.7 | 301.0 | 136.0/286.0 | Neg | – | – |
| 50 | Luteolin | 36.7 | 284.8 | 151.0/175.0 | Neg | – | – |
| 51 | Genistein | 36.9 | 269.0 | 135.0 | Neg | – | – |
| 52 | Kaempferol | 37.9 | 285.0 | 239.0 | Neg | – | – |
| 53 | Apigenin | 38.2 | 268.8 | 151.0/149.0 | Neg | – | – |
| 54 | Amentoflavone | 39.7 | 537.0 | 417.0 | Neg | 0.006 ± 0.000 | 0.004 ± 0.000 |
| 55 | Chrysin | 40.5 | 252.8 | 145.0/119.0 | Neg | – | – |
| 56 | Acacetin | 40.7 | 283.0 | 239.0 | Neg | – | – |