Table 1. Effect of a Solvent on the Sulfur Content in DEAE-Cellulose Sulfates during Sulfation with Sulfamic Acid in the Presence of Urea at 90 °C for 3.0 h.
no. | solvent | permittivity | Kb | sulfur content (wt %) |
---|---|---|---|---|
1 | 1,4-dioxane | 2.3 | 1.2 × 10–17 | 10.1 |
2 | pyridine | 12.5 | 1.5 × 10–9 | 8.9 |
3 | morpholine | 7.3 | 2.1 × 10–6 | 7.2 |
4 | piperidine | 5.9 | 1.3 × 10–3 | 7.9 |
5 | diglyme | 7.4 | 2.0 × 10–18 | 9.4 |