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. 2021 Aug 24;14(17):4782. doi: 10.3390/ma14174782

Table 1.

Phosphine ligands of Milstein-type Ru–PNN complexes.

Entry Catalyst Co-Cat. Reaction Conditions PET
Conv. (%) 		Sel. (%)
T
(°C)		 H2 (bar) Solvent t(h)
1 graphic file with name materials-14-04782-i001.jpg Kt-BuO 160 54 Anisole
THF		 48 99 100 1
2 graphic file with name materials-14-04782-i002.jpg HNTf 140 100 Dioxane 16 42 64 1
3 graphic file with name materials-14-04782-i003.jpg HNTf 140 100 Dioxane 16 64 99 1
4 Ru/Nb2O5 / 220 / H2O 12 91 100 2
5 Ru/Nb2O5 / 200 3 H2O 12 95 100 2

1 Selectivity to BDM. 2 Selectivity to BTX.