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. 2021 Aug 26;3(9):4347–4374. doi: 10.1021/acsapm.1c00654

Table 2. Commonly Used Ion Selectivity Definitions in the Literature.

symbol equation description
Pji(184) or Sj190
graphic file with name ap1c00654_m001.jpg
Ji and Jj are the flux (in mol·m–2·s–1) of the target and competing ions, respectively. ci and cj (in mol/L) are the concentrations of the target and the competing ion on the diluate side, respectively.
Fji(188),a
graphic file with name ap1c00654_m002.jpg
Ji and Jj are the flux (in mol·m–2·s–1) of the target and competing ions, respectively, when the source phase contains equal concentrations of the target and the competing ions.
ρji183 or βj197
graphic file with name ap1c00654_m003.jpg
ci,0 and ci,f are initial and final concentrations of the target ion. cj,0 and cj,f are initial and final concentrations of the competing ion.
Rji(190)
graphic file with name ap1c00654_m004.jpg
Ri and Rj are the resistance (in Ω·cm2) of the target and the competing ion, respectively.
a

In literature, there is no symbol used for this type of selectivity; here, we introduce F for matters of clarity.