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(top) established catalysts known to promote reductive SET events through electron-primed photoredox catalysis and (bottom) electrochemically driven electron-primed photoredox catalysis and a new catalyst discovered in this work derived from 4-DPAIPN. Ar = 2,6-diisopropylphenyl. R = p-OMePh. R' = 2-ethylhexyl.
