Table 6. Summary of Chemical Constituents Identified in the Standardized Botanical Supplement by LC–MS/MS.

							m/z observed
sr.no.	retention time (Rt)	Rf	(λmax)a	peak number	MFb	MWc	+ve mode	–ve mode	references
1	2.943		208	AP1	unknown		349, 367	345, 355
2	3.115		212	AP2	unknown		348, 370
3	3.640		225, 262	AP3	C16H24O8	344	345, 367		(30)
4	3.866		231, 286	AP4	C16H28O8	348	371, 387	391	(30)
5	3.982			FL5	kaempferol-3.7.4′-triglucoside	773	773, 795	771, 817	(30, 35, 36)
6	4.121		238	AP6	C20H30O13	478	501	523	(30)
7	4.367		241	AP7	C20H30O13	478	501		(30)
8	4.648		245	AP8	unknown	434	435, 467
9	4.821		245	AP9	C20H30O13	332	355, 371	377
10	5.013		242	AP10	(C16H26O8)	346	369, 385, 410	391, 417	(30)
11	5.400		249	AP11-12	C14H20O8	316	355, 317, 339	361, 429	(30)
12	5.596		248	AP13	C22H36O12	492	515	537	(30)
13	6.019		248	AP14	unknown	360	383	473
14	6.680		247	AP15	unknown	330	353,	376, 365, 443
15	6.901		254	AP16	unknown	343	366, 406	387
16	7.172	0.63	250	AP17	picrocrocin	330	353, 369, 399	376, 365, 443	(30, 36)
17	7.563		244, 262	CR18	unknown	453	454, 476	565, 497, 566
18	7.856	0.53	442	FL19	kaempferol-3-sophoroside	610	611, 633	609, 610, 655	(30, 38, 39)
19	8.119		439	CR20	trans-5-tG-crocin	1138	329, 635, 1161	1183	(35, 38)
20	8.273		418, 436	CR21	trans-5-nG-crocin	1138	329, 635, 1161	1183	(28, 30)
21	8.530	0.16	440, 463	CR22	trans-4-GG-crocin	976	329, 681, 999,	723, 533, 1021	(28−30, 36, 37, 40)
22	8.725		439, 462	CR23	unknown		794, 816
23	8.925	0.33	437	CR24	trans-3-Gg-crocin	814	837, 832, 814, 815	859, 860, 849	(28−30, 36, 40)
24	9.28		440, 463	CR25	cis-5-tG-crocin	1138		1138	(48)
25	9.446		436	CR26	trans-2-G-crocin	652	329, 547, 675, 837	697, 765, 249	(28, 30, 37, 39, 40)
26	9.516		434	CR27	cis-5-nG-crocin	1138	329, 625, 837, 1139		(30, 43)
27	9.786		431	CR28	cis-4-GG-crocin	976	329, 508, 697, 735, 999	651, 975, 1089	(30, 37, 40, 43)
28	10.259		434, 457	CR29	trans-2-gg-crocin	652	329, 651, 675, 691	697, 651, 698	(30, 38−40)
29	10.279		433, 456	CR30	cis-3-Gg-crocin	814	329, 837, 675	697, 765, 859	(28, 30, 33, 37)
30	10.880		252, 427	CR31	cis-2G-crocin	652	329, 541, 675	563, 631, 517	(30, 37, 40)
31	11.122		251, 426	CR32	trans-1-g-crocin	490	554, 329, 513	535, 525, 681	(28, 30, 40)
32	11.370		255, 432	CR33	cis-2-gg-crocin	652	274, 329, 675		(28, 30, 39)
33	11.984			FL34	dihydro kaempferol	288	288, 330	286, 354
34	13.486		425, 450	CR35	trans-crocetin	328	329, 594		(28, 30, 36, 43)
35	14.146		265	AP36	safranal	150	151, 192		(28, 30, 36, 39)

^aWavelength.

^bMolecular formula.

^cMolecular weight.