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. 2021 Sep 17;13(3):1385–1429. doi: 10.1007/s12649-021-01577-w

Table 4.

State of art synthesis of graphene [141]

Type Method Figure/Illustration Merits Challenges

Top-down

(from Graphite)

Mechanical exfoliation graphic file with name 12649_2021_1577_Figb_HTML.gif Less defects

Neither scalable nor capable

for mass production

Chemical method graphic file with name 12649_2021_1577_Figc_HTML.gif Cost-effective and suitable for mass production

Utilize many toxic chemical

throughout the synthesis

process

Bottom-up

Approach

(From Carbon)

Chemical Vapor Deposition (CVD) graphic file with name 12649_2021_1577_Figd_HTML.gif Compatible with the current complementary metal–oxide–semiconductor (CMOS) technology due to large area and high-quality graphene produced

Expensive and involves

complex transfer process

Epitaxial growth graphic file with name 12649_2021_1577_Fige_HTML.gif No defects for every single graphene island Discontinuous