(p)PSS composition and quantum yields of pHPS 2 and pFPS 15.
| PSSUVa [%] | PSSVisb [%] | ϕOCUVc [%] | ϕOCUVd [%] | ϕCOVise [%] | ϕOC/ϕCOUVf | |
|---|---|---|---|---|---|---|
| pHPS 2 | 58–60 | 0 | 31 | 29 | 56 | 1.07 |
| pFPS 15 | 55–58 | 0 | 39 | 40 | 45 | 0.98 |
Photostationary state after irradiation with UV light, in % CF.
Photostationary state after irradiation with Vis light, in % CF.
Ring cyclization quantum yields at 325 nm and 300 nm, respectively.
Ring opening quantum yields at 325 nm and 300 nm, respectively.
Ring cyclization quantum yields at 505 nm and 567 nm, respectively.
Ratio of ring closing to ring opening quantum yields upon UV irradiation.