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Synthetic methodologies for the preparation of polyfluorinated biaryls through C(sp2)−C(sp2) bond‐forming reactions. Ar=(hetero)aryl group, ArF=polyfluorinated (hetero)aryl group, TM=transition metal, X and Y=(pro)nucleophile or (pseudo)halogen or H, FG=functional group, R=alkyl or aryl group, n=4–9.
