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. Author manuscript; available in PMC: 2021 Sep 21.
Published in final edited form as: ACS Chem Biol. 2020 Apr 6;15(4):856–861. doi: 10.1021/acschembio.0c00044

Table 1.

S-Succination Reaction Kinetics As a Function of Electrophile and pH

pH fumarate maleate 2-Br-succinae
rate (mM−1 min−1) 5 (1.1 ± 0.6) × 10−4 (1.6 ± 0.78) × 10−4 (0.08 ± 0.01) × 10−4
6 (0.11 ± 0.03) × 10−4 (2.9 ± 0.66) × 10−4 (0.99 ± 0.23) × 10−4
7 (0.06 ± 0.01) × 10−4 (3.9 ± 0.57) × 10−4 (4.2 ± 0.59) × 10−4