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. 2021 Sep 3;60(18):14116–14131. doi: 10.1021/acs.inorgchem.1c01503

Figure 5.

Figure 5

Optical (top) and chiroptical (bottom) superspectra of (R)-3 (red curves) and (S)-3 (blue curves). Measurement conditions: UV region, 0.17 mM in CHCl3, 0.1 cm cell; visible region, 0.17 mM in CHCl3, 1 cm cell; NIR region, 0.76 mM in CHCl3, 2 cm cell; VCD region, 4000–2000 cm–1 subrange, 0.06 M [(R)-2] and 0.04 mM [(S)-2] in CDCl3, 200 μm cell; VCD region, 2000–900 cm–1 subrange, 35 mM in CDCl3, 200 μm cell. See Materials and Methods for further details.