. 2021 Sep 3;60(18):14116–14131. doi: 10.1021/acs.inorgchem.1c01503

Table 1. Ligand Chirality and Substituents Leading to Chirality Induction-At-Metal in Bis[(R or S)-N-1-(p-X-C₆H₄)ethyl-2-oxo-1-naphthaldiminato-κ²N,O]-Λ- or Δ-M(II) in the Solid State and Solution.

complex [M-(R or S-L)]	ligand substituent (X)	ligand chirality → induction-at-metal in the solid state	ligand chirality → induction-at-metal in solution	ref
M = Co	H (A/B)^a	S → Δ, R → Λ	S → Δ, R → Λ	this work
	p-CH₃O	R → Λ	R → Λ
	p-Br (A/B)^a	S → Δ	S → Δ
M = Cu	H	S → Δ, R → Λ	S → Δ, R → Λ	(20)
	m-CH₃O^b	R → Λ/Δ
	p-Br	R → Λ	R → Λ
M = Ni	H (A/B)^a	S → Δ, R → Λ	S → Δ, R → Λ	(21)
M = Zn	H (A/B)^a	S → Δ, R → Λ	S → Δ, R → Λ	(26)
	p-CH₃O (A/B)^a	S → Δ, R → Λ	S → Δ, R → Λ

Two symmetry-independent molecules A and B in an asymmetric unit with a single diastereomer (Λ or Δ).

Diastereomeric mixture with opposite Λ and Δ configurations in a single enantiopure crystal.

Table 1. Ligand Chirality and Substituents Leading to Chirality Induction-At-Metal in Bis[(R or S)-N-1-(p-X-C6H4)ethyl-2-oxo-1-naphthaldiminato-κ2N,O]-Λ- or Δ-M(II) in the Solid State and Solution.