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. 2021 Jul 1;60(37):20407–20416. doi: 10.1002/anie.202103641

Figure 10.

Figure 10

Illustration of how the surface of the [Bi38O45] cluster, with nitrate as the ligand, induces a solvent restructuring effect up to r=30 Å. Interactions between the bismuth oxido clusters and the DMSO molecules induce an ordering of the solvent molecules near the [Bi38O45] cluster surface, which gives rise to an exponentially dampened sinusoidal oscillation in the PDF. Carbon atoms are shown in black, sulfur in yellow, and hydrogen in beige.