Skip to main content
. 2021 Sep 8;6(37):23643–23653. doi: 10.1021/acsomega.1c03197

Table 5. Relationship between Propane Oxidation Reactions and Temperature/Pressure.

reactions relationship experimental validation ref
reactions of C3H8 + HO2(i) and C3H8 + O(ii) the relative contribution of reaction (i) increases with pressure, while that of reaction (ii) decreases jet-stirred flow reactor (46)
hydrocarbon reactions involved in the formation of the HO2 radical and the H2O2 molecule these reactions play a dominant role at temperatures lower than 1100 K and can reduce the ignition delay times shock tube (47)
some of the key reactions involving propylperoxy radicals these reactions are the key steps to control the rate of oxidation in the NTC region under high-pressure conditions high-pressure flow reactor (48)
reactions about H-abstraction by HO2 from propane the reaction of CH3 + HO2 inhibits ignition at the lower pressure of 10 bar; the reactions of C3H8 + OH accelerate ignition at 900 K but inhibit reaction at 1100 K laminar flow reactor, shock tube, rapid compression machine (49)