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Left: Crystal structure of FamD1 with 12 obtained by Wong et al.80 Looking down the β-barrel 12 and DMSPP are visible. Right: Structure of active site with Glu207 highlighted without forming a key hydrogen bond with 12. The loss of this hydrogen bond places 12 into a configuration favoring normal prenylation over reverse prenylation at indole C-2. Distances between carbons are also displayed.
