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(A) Example surfaces for DNA–polymer conjugation synthesis. Surfaces include whole macro materials in addition to precisely defined nanostructures. (B) Methods for CPG bead surface DNA–polymer synthesis through either the attachment of a (1) polymer phosphoramidite,121 (2) ATRP initiator phorphoramidite,13 (3) reactive handle phosphoramidite,9 and (4) monomer phorphoramidite.80
