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. Author manuscript; available in PMC: 2022 Sep 15.
Published in final edited form as: Org Biomol Chem. 2021 Sep 15;19(35):7575–7580. doi: 10.1039/d1ob01450a

Figure 1.

Figure 1.

Mechanistic Studies of the Baeyer-Mills Reaction (A) Baeyer-Mills reactions to generate azobenzenes are complicated by the production of azoxybenzene via a proposed nitrosobenzene reduction pathway. (B) Purified nitrosobenzene does not form azoxybenzene through disproportionation. (C) The aniline component of a Baeyer-Mills reaction is not incorporated into the azoxybenzene side product. (D) An electron-rich aniline facilitates the formation of azoxybenzene from nitrosobenzene.