Table 3.
1H and 13C NMR chemical shifts of Tmp (δ, ppm).
| Resides | H1/C1 | H2/C2 | H3/C3 | H4/C4 | H5/C5 | H6/C6 | O-Me |
|---|---|---|---|---|---|---|---|
| →2,5)-α-L-Araf-(1→ | 5.14/107.95 | 4.09/88.32 | 4.16/76.93 | 3.97/84.24 | 3.81/67.74 | 3.63/— | |
| →3,5)-α-L-Araf-(1→ | 5.04/107.25 | 4.04/82.40 | 4.04/84.69 | 3.75/79.23 | 3.59/67.69 | 3.81/— | |
| β-d-Glcp-(1→ | 4.75/103.26 | 3.33/70.27 | 3.63/75.3 | 3.81/70.27 | ND 1 | 3.86/62.02 | |
| α-d-Manp-(1→ | 4.96/102.99 | 4.04/71.57 | 3.81/72.23 | 3.37/75.28 | 3.61/68.63 | 3.81/63.34 | |
| α-d-Galp-(1→ | 4.90/99.86 | 3.78/71.45 | 4.16/70.17 | 3.61/74.44 | ND | 3.61/64.11 | |
| →4)-β-d-Galp-(1→ | 4.46/103.26 | 3.42/74.04 | 3.61/73.88 | 4.04/78.27 | 3.53/74.44 | 3.73/64.86 | |
| →3)-β-d-Glcp-(1→ | 4.75/104.54 | 3.47/74.44 | 3.70/85.78 | 3.45/69.83 | 3.42/76.73 | 3.81/62.02 | |
| →3)- α-d-Manp-(1→ | 5.04/102.99 | 4.16/70.93 | 3.99/78.23 | 3.78/68.63 | 3.81/75.86 | 3.73/62.45 | |
| →6)-3-O-Me-α-d-Manp-(1→ | 4.96/103.26 | 3.81/71.39 | 3.81/79.3 | 4.21/66.74 | 3.53/74.44 | 3.78/70.27 | 3.37/57.44 |
| →6)-α-d-Galp-(1→ | 4.95/99.53 | 3.56/72.62 | 3.78/71.89 | ND | ND | 3.75/70.93 | |
| →3,6)-β-d-Glcp-(1→ | 4.49/104.09 | 3.30/74.44 | 3.68/85.97 | 3.30/70.93 | 3.42/77.41 | 3.81/70.27 | |
| →6)-α-d-Manp-(1→ | 4.49/101.09 | 3.35/72.62 | 3.63/72.62 | 3.70/68.63 | 3.97/71.57 | 3.78/70.93 |
1 ND, signal was not detected.