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. 2021 Sep 13;13(18):3083. doi: 10.3390/polym13183083

Table 4.

Included studies with types of reinforcing agents used in PMMA heat-cured denture base resin and their outcomes corresponding to testing parameters.

Ref. Testing Method Reinforcing Agent/s Used Outcome
[28] FS, FT Treated 0.25 and 0.5 wt.% double-modified organoclay nanoparticles ↑↑ FS and FT in both 0.25 and 0.5 wt.% nanoparticles groups
[29] FS Ag, TiO2, ZrO2, Al2O3, SiC, SiC-nano, Si3N4, and HA-nano in ratios of 10 wt.% to PMMA ↔ between the study groups
[30] SH ZrO2 (14 nm), SiO2 (12 nm), and diamond nanoparticles (19 nm) in concentrations of 0%, 0.5%, 1.0%, 2.5%, and 5.0% by weight of acrylic powder ↑↑ in SH compared to Control
[31] FS, FM Microcrystalline cellulose with 2 or 5% by weight ↑↑ FS, FM in 5 wt.% group
[32] FS 1 wt.% or 5 wt.% of SiO2 or prepolymer nanoparticles ↓↓ FS in experimental groups compared to control group
[33] FS 1, 3, or 5 wt.% of Al2O3 (18 nm), SiO2 (15 nm), or TiO2 (13 nm) nanoparticles 1 wt.% of nanoparticles ↑↑ FS
[34] FS, EM, FT Polyvinyl alcohol aligned and non- aligned nanofiber with 0.05% w/w, 0.25% w/w, 1% w/w, or 1.25% w/w. Aligned nanofiber ↑↑ increased the mechanical properties of denture base resin
[35] FS Treated glass fillers (1%, 2.5%, 5%, and 10% by weight) 1.5 µm sized FS ↓ as glass filler uploading ↑
[36] FT Silanated nano barium titanate at 5 wt.% ↑↑ FT in the experimental group
[37] FS, FM Treated aramid fibers with four orientations (unidirectional, woven, non-woven, and paper-type) unidirectional and woven aramid fibers ↑↑ FS & FM
[38] FS, FM, FT GL, aramid, and UHMWPE fibers at volume concentrations of 2.6%, 5.3%, and 7.9%, respectively Combination of GL/UHMWPE fibers showed ↑↑ FT and FS
[39] FS GF, aramid, nylon at 4 wt.% (5 mm in length) ↑↑ FS in GF and aramid reinforced groups
[40] FR GF (chopped strand mat, continuous or woven) at 2.5, 3, 4, 5 vol.% ↑ fracture resistance in all forms of GF
[41] FS, FT, FM E-Glass FiBER FORCE ↑ mechanical properties were observed
[42] FS Treated and untreated ZrO2 nanotubes (8 µm in length) 2.0 wt.% ZrO2 nanotubes ↑ FS
[43] FS, SH Silane treated fine or coarse mica particles (30 µm and 131 µm) at 10 vol.% or 20 vol.% ↓ FS, however, ↑ SH with 20 vol.% mica reinforcement
[44] FS, FM Silanized nano SiO2 (36 nm in size) at 0.25, 0.5, 1, 5, 10, and 15 wt.% 1 wt.% presented ↑ FS while 10 % 15 wt.% showed ↑ FM
[45] FS, IS Nanodiamond (30–40 nm in size) at 0.5, 1, and 1.5 wt.% 0.5 wt.% reinforced PMMA displayed ↑↑ FS. Control group showed ↑↑ IS
[46] FS, SH 1, 2, 3, 4, 5, 10, 15, or 20 wt.% aluminum borate whiskers (5–30 µm in length) Silanized ABWs ↑ FS, SH. Optimal loading was 5 wt. % while 15 wt.% for SH
[47] SH, FT 0.023%, 0.046%, 0.091%, 0.23%, 0.46%, and 0.91% by vol. of SiO2 nanoparticles 0.023% resulted in ↑ SH and FT
[48] IS, FT 1% TiO2 and 1% ZrO2, 2% Al2O3, 2% TiO2, and 2% ZrO2 by volume IS and FT values ↑↑
[49] FS Silanized Al2O3 (0.1, 0.2, or 0.4 wt.%) 18–23 µm in size 0.1 wt.% Al2O3 showed ↑↑ FS
[50] TS, FS, CS 10%, 20%, and 30% by volume Ag and Al CS ↑↑ while TS and FS ↓ at 30 vol.%
[51] FS Treated S-glass fiber, nylon fiber ↑↑ in S-glass reinforced PMMA
[52] FS Hydrogen plasma-treated polypropylene fibers (2.5. 5 & 10 wt.%) ↑↑ FS in tested groups
[53] FS, IS, SH Borax, boric acid, colemanite The addition of 1% Colemanite to PMMA ↑ mechanical properties
[54] FS, EM, SH Halloysite nanotubes at 0.3, 0.6, and 0.9 wt.% 0.3 wt% halloysite nanotubes ↑ mechanical properties
[55] FS, SH Silanized nano ZrO₂ and nano aluminum borate whiskers at 1, 2, 3, and 4 wt.% The mechanical behaviours of silanized ZrO₂-ABW/PMMA composites ↑↑ improved
[56] FS, SH Treated 2.5 wt%, and 5 wt% of TiO2 nanotubes ↑↑ FS and SH in experimental groups

Key: ↑↑ = significant increase, ↑= increase, ↔ = no significant change, ↓ = decrease, ↓↓ = significant decrease, FRC = fiber reinforced composite, GL = glass, GF = glass fiber, UHMWPE = ultra high molecular weight polyethylene, FR = fatigue resistance, FS = flexural strength, SH = surface hardness EM = elastic modulus, IS = impact strength, FT = fracture toughness, FM = flexural modulus, TS = tensile strength, CS = compressive strength.