(A) Raw DSF measurements for KRAS G12C fully labeled with either ARS-632 or 1.
(B) First derivative of (A) shows the shifts in Tm (dashed vertical lines) associated with protein labeling.
(C) Impact of compound exposure on MAPK signaling. Levels of pERK were evaluated in the KRAS-G12C-containing cancer cell line H358 as a surrogate for RAS signaling through the MAPK pathway. Cells were treated with compound 1 or ARS-632 as indicated for 6 hr. Phosphorylation of ERK1/2 was determined by immunoblotting.