TABLE 1.
Peak, n. | Compound | Rt (min) | λmax(nm) | MS (m/z)[M + H]+ | MS/MS (m/z)[M + H]+ | FE | PE | ||||
---|---|---|---|---|---|---|---|---|---|---|---|
g IEa/100 g DE§ | |||||||||||
Betaxanthins | R | O | Y | R | O | Y | |||||
1 | Muscaaurin VII | 15.78 | 477 | 349 | 305 | 0.77 ± 0.10 | 1.16 ± 0.17 | 1.01 ± 0.04 | 1.47 ± 0.40 | 2.25 ± 0.79 | 1.12 ± 0.17 |
2 | Vulgaxanthin I | 19.25 | 475 | 340 | 323 | 1.52 ± 0.18 | 2.63 ± 0.09 | 1.56 ± 0.29 | 2.49 ± 0.35 | 3.96 ± 0.17 | 1.46 ± 0.19 |
3 | γ-aminobutyric acid-Bx | 23.62 | 467 | 297 | 253 | 0.23 ± 0.06 | 0.82 ± 0.19 | 0.81 ± 0.07 | 1.01 ± 0.27 | 1.10 ± 0.09 | 0.79 ± 0.02 |
4 | Indicaxanthin | 24.47 | 486 | 309 | 265 | 37.60 ± 4.18 | 98.01 ± 9.55 | 78.27 ± 5.77 | 22.27 ± 4.50 | 70.46 ± 9.96 | 50.18 ± 6.12 |
5 | Methionine-Bx | 27.95 | 477 | 343 | 299 | 0.37 ± 0.07 | 0.49 ± 0.07 | 0.63 ± 0.05 | 1.42 ± 0.25 | 0.47 ± 0.09 | 0.66 ± 0.10 |
Betacyanins | g BE°/100 g DE§ | ||||||||||
6 | Betanin | 25.88 | 538 | 551 | 389 | 18.94 ± 1.36 | 1.20 ± 0.04 | 1.16 ± 0.17 | 27.30 ± 5.85 | 2.45 ± 0.13 | 1.54 ± 0.08 |
7 | Isobetanin | 26.11 | 538 | 551 | 389 | 0.80 ± 0.12 | 0.08 ± 0.01 | 0.05 ± 0.01 | 1.67 ± 0.23 | 0.18 ± 0.04 | 0.09 ± 0.02 |
8 | Gompherenin I | 26.82 | 540 | 551 | 389 | 0.24 ± 0.04 | n.d. | n.d. | 0.74 ± 0.16 | 0.03 ± 0.00 | 0.04 ± 0.01 |
9 | Betanidin | 28.22 | 540 | 389 | 345 | 0.05 ± 0.01 | n.d. | n.d. | 0.21 ± 0.06 | 0.02 ± 0.00 | 0.01 ± 0.00 |
IE, indicaxanthin equivalents; §DE, dry extract; °BE, betanin equivalents.