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. 2021 Sep 14;12:722398. doi: 10.3389/fphar.2021.722398

TABLE 1.

Betalainic profile in red (R), orange (O), and yellow (Y) prickly pear flesh and peel extracts (FEs and PEs, respectively) by LC-DAD-ESI-MS/MS analysis. Results are expressed as mean ± standard deviations of ten independent experiments (n = 3).

Peak, n. Compound Rt (min) λmax(nm) MS (m/z)[M + H]+ MS/MS (m/z)[M + H]+ FE PE
g IEa/100 g DE§
Betaxanthins R O Y R O Y
1 Muscaaurin VII 15.78 477 349 305 0.77 ± 0.10 1.16 ± 0.17 1.01 ± 0.04 1.47 ± 0.40 2.25 ± 0.79 1.12 ± 0.17
2 Vulgaxanthin I 19.25 475 340 323 1.52 ± 0.18 2.63 ± 0.09 1.56 ± 0.29 2.49 ± 0.35 3.96 ± 0.17 1.46 ± 0.19
3 γ-aminobutyric acid-Bx 23.62 467 297 253 0.23 ± 0.06 0.82 ± 0.19 0.81 ± 0.07 1.01 ± 0.27 1.10 ± 0.09 0.79 ± 0.02
4 Indicaxanthin 24.47 486 309 265 37.60 ± 4.18 98.01 ± 9.55 78.27 ± 5.77 22.27 ± 4.50 70.46 ± 9.96 50.18 ± 6.12
5 Methionine-Bx 27.95 477 343 299 0.37 ± 0.07 0.49 ± 0.07 0.63 ± 0.05 1.42 ± 0.25 0.47 ± 0.09 0.66 ± 0.10
Betacyanins g BE°/100 g DE§
6 Betanin 25.88 538 551 389 18.94 ± 1.36 1.20 ± 0.04 1.16 ± 0.17 27.30 ± 5.85 2.45 ± 0.13 1.54 ± 0.08
7 Isobetanin 26.11 538 551 389 0.80 ± 0.12 0.08 ± 0.01 0.05 ± 0.01 1.67 ± 0.23 0.18 ± 0.04 0.09 ± 0.02
8 Gompherenin I 26.82 540 551 389 0.24 ± 0.04 n.d. n.d. 0.74 ± 0.16 0.03 ± 0.00 0.04 ± 0.01
9 Betanidin 28.22 540 389 345 0.05 ± 0.01 n.d. n.d. 0.21 ± 0.06 0.02 ± 0.00 0.01 ± 0.00
a

IE, indicaxanthin equivalents; §DE, dry extract; °BE, betanin equivalents.