Table 3.
The significant adjusted associations between short-term exposure to NO2 (predicted models) with metabolomics (multi-pollutant models) at ENT95% significance level
| Biochemical | Super-pathway | Sub-pathway | 1 day window, Beta (SE) for individual metabolites | 1 day window, p-value for individual metabolites | 7 day window, Beta (SE) for individual metabolites | 7 day window, p-value for individual metabolites | 30 day window, Beta (SE) for individual metabolites | 30 day window, p-value for individual metabolites | ICA_factor 2 Weight | ICA_factor 2 Rank |
|---|---|---|---|---|---|---|---|---|---|---|
| Hypotaurine | Amino Acid | Methionine, Cysteine, SAM and Taurine Metabolism | −0.013(0.003) | 4.62E-07 | NS | NS | NS | NS | 0.517134 | 20 |
| Maltotriose | Carbohydrate | Glycogen Metabolism | −0.017(0.004) | 7.11E-06 | −0.021(0.004) | 1.54E-06 | −0.022(0.005) | 6.54E-06 | 0.615801 | 9 |
| 3-phosphoglycerate | Carbohydrate | Glycolysis, Gluconeogenesis, and Pyruvate Metabolism | −0.016(0.003) | 5.82E-06 | NS | NS | NS | NS | 0.856077 | 2 |
| Nicotinamide | Cofactors and Vitamins | Nicotinate and Nicotinamide Metabolism | −0.012(0.002) | 6.3E-07 | NS | NS | NS | NS | 0.514755 | 22 |
| Dihomolinoleoylcarnitine (C20:2) * | Lipid | Fatty Acid Metabolism (Acyl Carnitine, Polyunsaturated) | −0.008(0.002) | 1.16E-05 | NS | NS | NS | NS | 0.354472 | 66 |
| Palmitoloelycholine | Lipid | Fatty Acid Metabolism (Acyl Choline) | 0.014(0.003) | 5.83E-06 | NS | NS | NS | NS | −0.44944 | 37 |
| Palmitoylcholine | Lipid | Fatty Acid Metabolism (Acyl Choline) | 0.013(0.003) | 9.48E-06 | NS | NS | NS | NS | −0.47882 | 30 |
| Oleoylcholine | Lipid | Fatty Acid Metabolism (Acyl Choline) | 0.014(0.003) | 3.33E-06 | NS | NS | NS | NS | −0.48131 | 28 |
| Stearoylcholine * | Lipid | Fatty Acid Metabolism (Acyl Choline) | 0.015(0.003) | 1.4E-05 | NS | NS | NS | NS | −0.5512 | 15 |
| 8-hydroxyoctanoate | Lipid | Fatty Acid, Monohydroxy | 0.013(0.003) | 1.02E-05 | NS | NS | NS | NS | −0.30251 | 95 |
| Linolenate [alpha or gamma; (18:3n3 or 6)] | Lipid | Long Chain Polyunsaturated Fatty Acid (n3 and n6) | NS | NS | −0.01(0.002) | 8.52E-06 | NS | NS | 0.055594 | 500 |
| Palmitate (16:0) | Lipid | Long Chain Saturated Fatty Acid | NS | NS | −0.008(0.002) | 7.3E-06 | NS | NS | 0.059332 | 473 |
| 1-stearoyl-2-oleoyl-GPS (18:0/18:1) | Lipid | Phosphatidylserine (PS) | −0.013(0.003) | 6.87E-06 | NS | NS | NS | NS | 0.640158 | 8 |
| Phosphoethanolamine | Lipid | Phospholipid Metabolism | −0.012(0.002) | 5.48E-07 | NS | NS | NS | NS | 0.551825 | 14 |
| Choline phosphate | Lipid | Phospholipid Metabolism | −0.009(0.002) | 2.84E-06 | NS | NS | NS | NS | 0.422478 | 46 |
| Sphingadienine | Lipid | Sphingolipid Synthesis | −0.015(0.003) | 1.81E-06 | NS | NS | NS | NS | 0.696453 | 6 |
| Sphingosine | Lipid | Sphingosines | −0.011(0.002) | 8.05E-06 | NS | NS | NS | NS | 0.56189 | 13 |
| Adenosine 5’-monophosphate (AMP) | Nucleotide | Purine Metabolism, Adenine containing | −0.015(0.003) | 4.08E-06 | NS | NS | NS | NS | 0.796578 | 4 |
| X - 18914 | Xenobiotics | Chemical | NS | NS | NS | NS | −0.01(0.002) | 3.99E-06 | 0.099545 | 274 |
These models were linear mixed-effect regression models (LMEM) with random participant-specific intercepts and simultaneously adjusted for PM2.5, NO2, O3, and temperature (multi-pollutant models) for the same exposure window.
Beta (SE) and p-values presented are from individual metabolites analysis.
All models were adjusted for age (years), body mass index (kg/m2), cigarette pack-years, alcohol intake (< or ≥2 drinks per day), socioeconomic status (income payment and years of education), season (warm/cold), and relative humidity.
Significant metabolites at ENT95% significance level only are presented.
ICA_factor2 rank represents the rank of the corresponding metabolite contributing to factor 2 from the independent component analysis (ICA). Higher rank (and higher weights) means higher contribution to factor 2 of the ICA. We show alongside the weights and ranks of each metabolite that contributes to factor 2 from the ICA only because it was the only significant factor.
Range of facto2-ICA rank is from 1 to 1158 i.e., number of examined metabolites. Range of facto2-ICA weight is from −1 to 1.
The metabolites with an X-XXXX format are unknown but reproducible.
A single asterisk after a metabolite (*) indicates a compound that has not been confirmed based on a standard, but Metabolon is confident in its identity based on a subset of these analytical parameters.
Abbreviations: ENT: Effective/independent number of tests; PM2.5, particulate matter ≤2.5 μm; NO2, nitrogen dioxide; and O3, ozone; ICA, independent component analysis; SE, standard error.