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Conversions determined by HPLC.
Transaminase T039/BAL (see Scheme 5).
BCAT/AspAT system (see Scheme 6).
Isolated yield.
dr >95:5 as measured by NMR; no other diastereomers were detected.
dr 50:50 as measured by NMR.
dr 60:40 (S:R) as measured by NMR.
