Table 4. Arrhenius Fits in the Form AT^α exp(−E_A/RT)^a.

P (atm)	A (cm3 mol–1 s–1)	α	EA (cal/mol)	R2	T range (K)
C6H6 + O → C6H5O + H
0.1	1.34 × 108	1.76	5620	1.00	300–2200
1	1.04 × 108	1.79	5600	1.00	300–2200
10	2.91 × 108	1.66	5880	1.00	300–2200
100	6.67 × 109	1.28	6930	1.00	300–2200
C6H6 + O → CO + C5H6
0.1	6.09 × 1015	–0.91	9840	0.99	300–2200
1	2.22 × 1018	–1.58	14800	1.00	300–2200
10	3.01 × 1019	–1.83	20300	1.00	800–2200
100	5.63 × 1002	2.87	12900	0.99	1000–2200
C6H6 + O → C6H5OH (Original)
0.1	1.80 × 1016	–6.73	–14031	0.98	300–1500
1	3.49 × 1012	–0.78	1200	0.99	300–1500
10	1.97 × 1023	–3.11	8560	1.00	500–1750
100	5.61 × 1021	–2.63	7900	1.00	300–2000
C6H6 + O → C6H5OH (Duplicate)
0.1	1.40 × 1038	–7.68	14400
1	1.05 × 1028	–4.55	10500
10	1.46 × 1032	–6.88	7500
100	7.90 × 1033	–7.60	7500

^aUnits: cal, mol, s, cm³. In the fitting, the rate constants for all of the collisionally-stabilized wells (mainly ¹W1, ¹W2, and ¹W7) were merged into that of phenol (¹W1).