Skip to main content
. 2021 Sep 22;77(Pt 10):1218–1232. doi: 10.1107/S2059798321008809

Table 3. General properties of pHP photocages, highlighting the effect of adding electron-donating groups to the ring (Klán et al., 2013).

The ligand released by photocleavage is represented by LG.

       
  graphic file with name d-77-01218-scheme9.jpg graphic file with name d-77-01218-scheme10.jpg graphic file with name d-77-01218-scheme11.jpg
λmax (nm) 285 280 304
ɛmax (M −1 cm−1) ∼15000 ∼9000 ∼12000
φ 0.2–0.9 0.03–0.04 0.03
k (s−1) 1 × 107 to 2 × 109 ∼2 × 109 ∼2 × 107
Solubility (H2O) Good Good Good