Table 3. General properties of pHP photocages, highlighting the effect of adding electron-donating groups to the ring (Klán et al., 2013 ▸).
The ligand released by photocleavage is represented by LG.
|
|
|
|
|---|---|---|---|
| λmax (nm) | 285 | 280 | 304 |
| ɛmax (M −1 cm−1) | ∼15000 | ∼9000 | ∼12000 |
| φ | 0.2–0.9 | 0.03–0.04 | 0.03 |
| k (s−1) | 1 × 107 to 2 × 109 | ∼2 × 109 | ∼2 × 107 |
| Solubility (H2O) | Good | Good | Good |