Table 3. Enantioselective Aza-IEDDA between Diene 1 and Trimethyl(styryloxy)silane 2b^a.

^aAll of the reactions were performed on a 0.05 mmol scale of 1 in 0.3 mL of THF at rt. Diastereomeric ratios were determined by ¹H NMR of the crude mixture. Enantiomeric excesses were determined by SFC chromatography.