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. 2021 Oct 5;94(7):847–872. doi: 10.1134/S1070427221070016

Table 1.

Affecting parameters on morphology of electrospun polymer nanofibers [21]

Parameters Effect on fiber morphology
Solution parameters
↑ Molecular weight of polymer

↓ Beads and droplet formation

Formation of irregular shape with larger pores

↑Polymer concentration (viscosity)

↓ Bead formation

↑Fiber diameter (within optimal range)

↑Solution conductivity

↓ Uniform bead-free fibers

Fiber diameter with broad diameter distribution

↑Solvent volatility Generation of pores on the surface fiber (microtexture)
Processing parameters
↑Applied voltage ↑↓ First fiber diameter, after that with bead formation

↑Distance between tip and collector

(working distance)

↓ Fiber diameter

Bead formation occurs in too short or too far distance

Minimum distance is required for uniform fibers generation

↓ Feed rate/flow rate

↓ Fiber diameter

Bead formation with very high feed rate

Ambient parameters
↑Temperature ↓↓ Fiber diameter and viscosity
↑Humidity Generation of circular pores on the fibers
↑Air velocity ↑Fiber diameter