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. Author manuscript; available in PMC: 2022 Aug 7.
Published in final edited form as: Biomater Sci. 2021 Jun 7;9(15):5069–5091. doi: 10.1039/d1bm00423a

Figure 4.

Figure 4.

Grafting-from AMP-polymer conjugation: a) NCA ROP scheme and an example ROP of lysine (lys) and valine (val) NCA monomers from PAMAM dendrimers, adapted with permission from Lam et al.,103 copyright © 2016 American Chemical Society; b) RAFT polymerization scheme and an example of grafting poly(2-hydroxyethylmethacrylamide) from an AMP-functionalized chain transfer agent (CTA), adapted with permission from Luppi et al.,104 copyright © 2019 The Royal Society of Chemistry; c) ATRP and d) NMP schemes and sequential polymerization of tert-butyl acrylate and styrene from a resin-bound AMP. Subsequent removal of the conjugates from the resin and removal of tert-butyl groups yielded AMP-poly(acrylic acid)-block-polystyrene conjugates. Adapted with permission from Becker et al.,105 copyright © 2005 American Chemical Society.