Table 4. Kinetic Parameters for Adsorption of the MB Dye onto RC-nZVI.
concentration (mg·L–1) |
|||||
---|---|---|---|---|---|
parameter | 25 | 50 | 100 | 150 | 200 |
qe,exp (mg·g–1) | 8.10 | 15.46 | 30.40 | 43.33 | 53.16 |
pseudo-first-order | |||||
qe, cal (mg·g–1) | 8.78 | 18.14 | 31.16 | 39.10 | 55.76 |
K1 (min–1) | 0.046 | 0.033 | 0.035 | 0.027 | 0.019 |
R2 | 0.988 | 0.975 | 0.971 | 0.961 | 0.961 |
(χ2) | 0.944 | ||||
pseudo-second-order | |||||
qe cal (mg·g–1) | 15.34 | 28.18 | 43.22 | 66.46 | 155.4 |
K2 (mg·g–1) | 0.0038 | 0.0021 | 0.0012 | 0.0014 | 0.0002 |
R2 | 0.907 | 0.949 | 0.970 | 0.910 | 0.831 |
(χ2) | 34.529 | ||||
Elovich | |||||
β (g·mg–1) | 0.328 | 0.171 | 0.102 | 0.103 | 0.050 |
α (mg·g·min–1) | 0.575 | 1.612 | 2.393 | 2.92 | 5.779 |
R2 | 0.944 | 0.961 | 0.970 | 0.920 | 0.918 |