Table 2. Composition of Layers as Obtained from Quantitative Analysis of Spectra Shown in Figure 3a.
| CCF3 | Chetero | Calkyl | OSO3 | FCF3 | |
|---|---|---|---|---|---|
| nominal | 1 | 3 | 2 | 3 | 3 |
| (a) Au(111): RT | 1.2 | 2.8 | 1.8 | 2.7 | 3.5 |
| (b) Ag(111): RT | 1.4 | 2.0 | 1.3 | 3.6 | 4.1 |
| (c) Ag(111): 90 K | 0.9 | 3.0 | 2.0 | 3.1 | 3.0 |
| (d) Ag(111): 90 K → RT | 1.7 | 0.7 | 0.4 | 4.2 | 5.1 |
a
(a) Saturated wetting layer of [dema][TfO] on Au(111) deposited at RT (black); (b) saturated wetting layer layer of [dema][TfO] on Ag(111) deposited at RT (black); (c) 0.5 ML of [dema][TfO] on Ag(111) deposited at 90 K (blue); (d) after heating this film from 90 K to RT (green).