Table 3.
Wavelength (λmax), excitation energy (E) and oscillator strength (fos) of investigated compounds in chloroform.
| Compounds | λmax (nm) | E (eV) | fos | MO contributions |
|---|---|---|---|---|
| TPDR | 658.89 (632)a | 1.88 | 2.42 | H → L (95%) |
| TPD1 | 741.93 | 1.67 | 2.31 | H → L (96%) |
| TPD2 | 757.11 | 1.63 | 2.31 | H → L (96%) |
| TPD3 | 739.63 | 1.67 | 2.27 | H → L (96%) |
| TPD4 | 810.78 | 1.53 | 2.25 | H → L (96%) |
| TPD5 | 714.56 | 1.73 | 1.54 | H → L + 2 (96%) |
| TPD6 | 748.65 | 1.65 | 2.05 | H → L (95%), |
MO molecular orbital, H HOMO, L LUMO.
aExp. value in parentheses30.