Table 1.
Sr. No. | Reaction conditions | Time (h) | Yield of 1 (%) |
---|---|---|---|
1 | Ru(bpz)3(PF6)2 (0.1 equiv), (NH4)2S2O8 (2 equiv), CH3CN, Ar, blue LED, r.t | 18 | Decomposed |
2 | Acridinium (0.1 equiv), TBHP (2 equiv), CH3CN, Ar, blue LED, r.t | 48 | Decomposed |
3 | CAN (2.5 equiv), CH3CN, Ar, 0 °C | 2 | Decomposed |
4 | Mn(OAc)3·2H2O (4 equiv), CH3CN, Ar, reflux | 5 | Decomposed |
5 | PIFA (1.2 equiv), HFIP, Ar, r.t | 4 | Decomposed |
6a | Glassy carbon anode, Glassy carbon cathode, 0.1M LiClO4, 1.25 V | 18 | – |
7a | Platinum anode, Glassy carbon cathode, 0.1MLiClO4,1.25 V | 10 | – |
aPassivation of electrode observed.