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. 2021 Aug 5;8(19):2100774. doi: 10.1002/advs.202100774

Table 2.

Electrode materials for cathode

No Name Composition of electrodea) Potential (V vs Li+/Li) Specific capacity [µAh cm−2µm−1] Deposition method/temperature [°C] Refs.
1 Titanium oxysulfide TiOS 2.25 dc‐reactive sputtering/T r [ 206 ]
2 Titanium oxysulfide TiSi x O y rf‐sputtering/T r [ 174 ]
3 Titanium sulfide TiSi2 2.5 rf‐sputtering/T r [ 175 ]
4 [ 207 ]
5 Silver iodide AgI 2.1 [ 3 ]
6 Lithium cobalt oxide LiCoO2 3.5–3.9 PLD/T r, postannealed 400–850 [ 208 ]
7 LiCoO2 3.5 50 PLD/T r, postannealed 800 [ 208 ]
8

LiCoO2

LiCo1‐ x Al x O2

3.8 PLD / 300–700 [ 209 ]
9 LiCoO2

200

mAh g−1

rf‐sputtering/ <180 (amorphous) [ 210 ]
10

LiCoO2 (LE)

LiCo1‐ x Al x O2 (LE)

89

mAh g−1

89/3

mAh g−1

PLD/700

PLD/600

[ 211 ]
11 LiCoO2 (LE) 3.5 195 mC cm−2 µm−1 PLD/100–300 [ 212 ]
12 3.9 PLD [ 213 ]
13 52.5 rf‐sputtering (350 °C) with rf plasma treatment [ 214 ]
14 60 rf‐sputtering/up to 500 [ 215 ]
15 48 Sol‐gel, annealed 600–800 [ 199 ]
16 67 rf‐sputtering/T r, postannealed 500 [ 216 ]
17 LiNi0.8Co0.2O2 3.7

89

mAh g−1

PLD/500–900, postannealed 1000 [ 217 ]
18 Lithium nickel‐manganese‐cobalt oxide Li(Ni x Mn y Co z )O2 (LE) 4.2–3.9 164 mAh g−1 rf‐sputtering / postannealed 700 [ 218 ]
19
20 Li(Ni x Mn y Co z )O2 3.8–3.5 33
21 Li(Ni1/3Mn1/3Co1/3)O2 177 mAh g−1 PLD/ postannealed 450 [ 219 ]
22 Lithium‐rich nickel‐manganese‐cobalt oxide xLi2MnO3‐(1‐x) Li(Mn0.375Ni0.375Co0.25)O2 (LE) 4.5–2 Spin coat/postannealed 450 [ 220 ]
23 Li[Li0.2Mn0.54Co0.13Ni0.13]O2 45 rf‐sputtering/T r, post annealed 450–600 [ 221 ]
24 LiCoBO3 (LE) 3.5–2.5 [ 222 ]
25 Li1+ x V3O8 2.9 Li1+ x V3O8‐polyethylene oxide composite [ 223 ]
26 Li1+ x V3O8 (LE) 3.8–1.5 250 mAh g−1 rf‐sputtering (mixed amorphous and crystalline) [ 224 ]
27 LiV2O5 3.5 30 Plasma enhanced chemical vapor deposition/250 [ 225 ]
28 Lithium manganese oxide LiMn2O4 (LE) 4.0 rf‐sputtering/T r, postannealed 650–800 [ 207 ]
rf‐sputtering/T r, postannealed 400 [ 226 ]
PLD / 500 [ 227 ]
29 LiMn2O4 4.2 50 Reactive electron beam evaporation/50 (substrate), postannealed 800 [ 228 ]
30 47 rf‐sputtering/T r, postannealed 750 [ 229 ]
31 4.1–3.9 80 mAh g−1 rf‐sputtering/T r, postannealed 750 [ 230 ]
32 Li x Mn2‐ y O4 (LE) 4.1–3.9 121 mAh g−1 rf‐sputtering/T r with bias [ 231 ]
33 LiMn2O4 (LE) 4.1 rf‐sputtering/T r, postannealed 700 [ 232 ]
34 Sol‐gel combined with oxygen‐plasma irradiation/ 723, 973 K [ 233 ]
35 Chemical solution deposition/postannealed 500–750 [ 234 ]
36 4.0, 3.0 1.2 Ah cm−3 rf‐sputtering/T r, postannealed 800 [ 236 ]
37 LiSn0.0125Mn1.975O4 (LE) 4.2 68 rf‐sputtering/T r, postannealed 500 [ 235 ]
38 LiMn2O4/SrRuO3 (LE) 4.1 125 mAh g−1 PLD/650 [ 237 ]
39 Lithium nickel manganese oxide LiNi0.5Mn1.5O4 (LE) 4.7 155 mAh g−1 Electrostatic spray deposition/450, postannealing 700 [ 238 ]
40 4.7 45 Sol‐gel/post annealed 500–700 [ 239 ]
41 4.8 120–155 mAh g−1 PLD/600 [ 240 , 241 , 242 , 243 , 244 , 245 , 246 ]
42 5 & 4 120 mAh g−1 rf‐sputtering/T r, [ 247 ]
43 4.7 50 rf‐sputtering/T r, postannealed 700 or 750 [ 248 ]
44 4.7 104 mAh g−1 rf‐sputtering/T r, post annealed 600 [ 249 ]
45 LiNi0.5Mn1.5O4 4.8 PLD/ 500, 650 [ 250 ]
46 LiCoMnO4 (LE) 5 110 mAh g−1 PLD/500 [ 251 ]
47 Lithium iron phosphate LiFePO4 (LE) 3.4 PLD/Tr , postannealed 773 K [ 252 ]
48 160 mAh g−1 PLD/600 [ 253 ]
49 PLD/500 [ 254 ]
50 33 rf‐sputtering/T r, 500 [ 255 ]
51 56 rf‐sputtering/up to 500 [ 256 ]
52 Lithium cobalt phosphate LiCoPO4 4.8 rf‐sputtering/T r, postannealed 300–700 [ 257 ]
53 Vanadium pentoxide V2O5 3.7 dc sputtering/T r [ 207 ]
54 3–2 43 Thermal evaporation [ 258 ]
55 V2O5 (LE) 3.4 PLD/T r, 500 [ 211 ]
56 ALD / postannealed 400 [ 259 ]
57 Mangenues dioxide MnO2 3 rf‐sputtering/T r, postannealed up to 450 [ 260 ]
58 Molybdenum oxide MoO3‐ x 3–1.9 85 rf‐sputtering/100 [ 261 ]
59 Molybdenum oxysulfide MoS x O y 2.4–1.3 Electrochemical deposition [ 262 ]

a)ATFBs were tested based on full cells unless otherwise stated as “LE” indicating half‐cell using the liquid electrolyte.