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The unit cell parameters derived from the SPD and NPD data of the compounds BiMnO3+δ with δ = 0.02, 0.08, 0.14 - (a–c), respectively. The DSC curves obtained for the respective compounds are presented at the bottom. The unit cell parameters are presented in normalized form, viz. ap = a/√6, bp = b/√2, cp = c/√6·(for C2/c and P21/c phases) and ap = a/√2, bp = b/4, cp = c/(2√2)·(for Pnma phase).
