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. Author manuscript; available in PMC: 2022 Aug 11.
Published in final edited form as: J Am Chem Soc. 2021 Jul 27;143(31):11939–11945. doi: 10.1021/jacs.1c05764

Scheme 1. Reported organosilane reactions with aryl electrophiles and development of base-promoted arylation.

Scheme 1.

aYields determined by 1H NMR spectroscopy; 18-crown-6 added as a 1M solution in THF. 18 h time for salts other than CsF. bYields improve to 57% and 84% at 100 °C without 18-crown-6 for Cs2CO3 and KF, respectively.