Table 1.
Ionic Liquid | Concentration (M) | R | Average Diameter (µm) | Std. Dev. (µm) | Comments | PDI (%) | Yield (Droplets/mm2) |
---|---|---|---|---|---|---|---|
SDS | 0.02 | 5 | 107 | 19 | Dominant radial configuration until R = 65, after which escaped radial is dominant | 17 | 60 |
20 | 110 | 35 | 12 | 27 | |||
35 | 100 | 22 | 7 | 27 | |||
50 | 86 | 30 | 14 | 19 | |||
65 | 43 | 34 | 22 | 8 | |||
80 | 56 | 33 | 16 | 11 | |||
95 | 48 | 25 | 24 | 0 | |||
0.2 | 5 | 103 | 12 | Mixture of radial and escaped radial | 33 | 28 | |
20 | 94 | 8 | 21 | 29 | |||
35 | 91 | 13 | 19 | 19 | |||
50 | 82 | 6 | 8 | 11 | |||
65 | 81 | 6 | 8 | 8 | |||
80 | 80 | 4 | 8 | 7 | |||
95 | 79 | 8 | 8 | 6 | |||
C12MIMCl | 0.02 | 5 | 102 | 10 | Radial configuration across all ratios | 10 | 40 |
20 | 105 | 26 | 24 | 31 | |||
35 | 94 | 16 | 17 | 35 | |||
50 | 87 | 9 | 11 | 30 | |||
65 | 85 | 8 | 10 | 21 | |||
80 | 80 | 6 | 7 | 19 | |||
95 | 74 | 6 | 8 | 21 | |||
0.2 | 5 | 98 | 18 | Mixture of radial and escaped radial | 18 | 70 | |
20 | 93 | 22 | 23 | 25 | |||
35 | 81 | 12 | 15 | 16 | |||
50 | 75 | 11 | 15 | 15 | |||
65 | 73 | 11 | 16 | 11 | |||
80 | 72 | 12 | 17 | 9 | |||
95 | 71 | 14 | 20 | 10 | |||
0.4 | 5 | 115 | 43 | Escaped radial | 38 | 101 | |
20 | 120 | 57 | 47 | 30 | |||
35 | 88 | 15 | 17 | 18 | |||
50 | 79 | 12 | 15 | 13 | |||
65 | 81 | 12 | 14 | 20 | |||
80 | 78 | 23 | 29 | 6 | |||
95 | 77 | 17 | 22 | 7 | |||
C10MIMCl | 0.02 | No droplets were formed | |||||
0.2 | No droplets were formed | ||||||
0.4 | 5 | 99 | 54 | Mixture of different configurations | 55 | 4 | |
20 | 115 | 56 | 49 | 6 | |||
35 | 130 | 44 | 34 | 2 | |||
50 | 131 | 37 | 28 | 1 | |||
65 | 85 | 22 | 26 | 6 | |||
80 | 101 | 26 | 26 | 3 | |||
95 | 106 | 15 | 15 | 1 | |||
C8MIMCl | 0.02 | No droplets were formed | |||||
0.2 | – | – | – | Mixture of different configurations | – | – | |
20 | 190 | 58 | 31 | 2 | |||
35 | 132 | 49 | 37 | 12 | |||
50 | 126 | 52 | 41 | 26 | |||
65 | 114 | 45 | 40 | 28 | |||
80 | 98 | 41 | 42 | 15 | |||
95 | 90 | 21 | 23 | 2 | |||
0.4 | – | – | – | Mixture of different configurations | – | – | |
20 | 160 | 80 | 50 | 0 | |||
35 | 132 | 87 | 66 | 3 | |||
50 | 111 | 35 | 31 | 13 | |||
65 | 96 | 30 | 31 | 13 | |||
80 | 102 | 25 | 25 | 3 | |||
95 | 103 | 31 | 30 | 21 |