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. 2021 Sep 29;26(19):5894. doi: 10.3390/molecules26195894

Table 2.

Energies, enthalpies and free energies of LAE hydrolysis reactions ΔEh. and their transition states ΔEt.

Hydrolysis Path Base Catalysed Acid Catalysed
Data ΔEt [kcal/mol] ΔEh [kcal/mol] ΔEt [kcal/mol] ΔEh [kcal/mol]
LAE → l-arginine ethyl ester + dodecanoate/dodecanoic acid energy 7.0 −10.3 20.7 11.2
enthalpy 6.4 −10.3 20.1 11.2
free energy 17.5 −15.6 31.3 9.0
LAE → LAS + ethanol energy −4.3 −21.6 12.8 5.7
enthalpy −4.3 −21.6 12.2 5.7
free energy 4.9 −24.2 23.8 4.4