Table 2.
Hydrolysis Path | Base Catalysed | Acid Catalysed | |||
---|---|---|---|---|---|
Data | ΔEt [kcal/mol] | ΔEh [kcal/mol] | ΔEt [kcal/mol] | ΔEh [kcal/mol] | |
LAE → l-arginine ethyl ester + dodecanoate/dodecanoic acid | energy | 7.0 | −10.3 | 20.7 | 11.2 |
enthalpy | 6.4 | −10.3 | 20.1 | 11.2 | |
free energy | 17.5 | −15.6 | 31.3 | 9.0 | |
LAE → LAS + ethanol | energy | −4.3 | −21.6 | 12.8 | 5.7 |
enthalpy | −4.3 | −21.6 | 12.2 | 5.7 | |
free energy | 4.9 | −24.2 | 23.8 | 4.4 |