Table 1.
Mean Concentration (μg. g−1 DW) and relative standard deviation (%) of volatile compounds in citrus peel extracts from Navelina (Citrus sinensis L. Osbeck cv. “Navelina”), Salustriana (Citrus sinensis L. Osbeck cv. “Salustriana”), and Sanguina (Citrus x sinensis var. “Sanguina”), fresh, oven-dried (50 °C, 70 °C), and freeze-dried (FD).
| KI | COMPOUNDS | Navelina Peel | Salustriana Peel | Sanguina Peel | |||||||||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Mean Fresh | RSD | Mean FD | RSD | Mean Oven 50 °C | RSD | Mean Oven 70 °C | RSD | Mean Fresh | RSD | Mean FD | RSD | Mean Oven 50 °C | RSD | Mean Oven 70 °C | RSD | Mean Fresh | RSD | Mean FD | RSD | Mean Oven 50 °C | RSD | Mean Oven 70 °C | RSD | ||
| Sesquitenenes | |||||||||||||||||||||||||
| 1476 | α-copaene | 1.54 a | (7.76) | 1.71 a | (10.91) | 0.52 b | (8.32) | 0.38 b | (12.97) | 1.58 a | (14.91) | 1.2 a | (16.90) | 0.44 b | (0.59) | 0.34 c | (7.16) | 2.37 a | (2.13) | 2.92 b | (5.07) a | 1.26 c | (6.93) | 1.82 d | (5.75) |
| 1630 | γ-elemene | traces | 0.29 a | (11.78) | 0.26 a | (7.18) | 0.71 b | (7.52) | traces | 0.56 a | (8.13) | 0.36 b | (3.61) | 0.57 a | (5.61) | 0.33 a | (7.56) | 0.73 b | (8.15) | 0.13 c | (8.63) | 0.27 d | (10.80) | ||
| 1654 | β-farnesene | traces | 0.58 a | (9.82) | 0.24 b | (3.55) | 2.17 c | (15.98) | traces | 0.50 a | (0.77) | 0.25 b | (0.71) | 0.55 a | (16.94) | 0.27 a | (10.17) | 0.21 a | (5.82) | 0.24 a | (9.51) | 0.46 b | (13.48) | ||
| 1701 | valencene | 35.43 a | (0.98) | 36.67 a | (12.97) | 30.2 b | (7.82) | 13.31 c | (10.29) | 21.75 a | (5.06) | 27.45 b | (7.76) | 25.16 ab | (7.99) | 22.63 a | (7.99) | 20.54 a | (7.63) | 26.4 b | (9.38) | 5.86 c | (10.07) | 12.58 d | (8.63) |
| 1704 | germacrene D | 0.44 a | (0.00) | 0.81 b | (6.73) | 0.44 a | (5.08) | 0.12 c | (8.29) | 3.32 a | (20.20) | 3.37 a | (6.88) | 2.31 b | (12.91) | 2.04 b | (7.31) | 0.11 a | (6.15) | 0.38 b | (0.31) | 0.05 c | (1.36) | 0.21 d | (4.85) |
| 1723 | α-farnesene | 0.51 a | (0.34) | 0.87 b | (12.97) | 0.56 a | (0.28) | 0.42 c | (4.98) | 1.09 a | (0.29) | 0.88 b | (11.05) | 0.43 c | (7.88) | 0.31 d | (0.26) | 0.68 a | (0.98) | 3.22 b | (8.07) | 0.62 ac | (9.51) | 0.73 c | (10.16) |
| 1740 | δ-cadinene | traces | 0.5 a | (11.47) | 0.19 b | (6.86) | 0.62 a | (11.78) | traces | 0.36 a | (3.96) | 0.21 b | (4.56) | 0.26 b | (3.01) | 0.34 a | (5.66) | 0.91 b | (2.11) | 0.13 c | (10.97) | 0.65 d | (6.86) | ||
| 2016 | nerolidol | 2.06 a | (8.15) | 2.28 a | (11.55) | 0.42 b | (5.82) | 0.30 c | (6.86) | 0.99 a | (7.99) | 0.84 a | (3.91) | 0.64 c | (4.07) | 0.41 d | (5.35) | 0.66 a | (7.83) | 0.91 b | (6.82) | 0.41 c | (12.97) | 0.46 c | (2.77) |
| 2236 | β-sinensal | 11.8 a | (6.86) | 14.08 b | (7.44) | 5.69 c | (7.52) | 3.65 d | (7.52) | 3.19 a | (8.63) | 3.36 a | (2.00) | 2.6 b | (0.01) | 2.15 c | (0.28) | 5.17 a | (7.76) | 7.47 b | (5.70) | 0.35 c | (3.85) | 1.38 d | (0.98) |
| 2331 | α-sinensal | 10.95 a | (12.55) | 13.77 | (14.14) a | 4.91 b | (10.05) | 3.01 c | (10.05) | 4.32 a | (18.69) | 4.18 a | (18.21) | 1.86 b | (0.01) | 1.62 b | (11.39) | 4.32 a | (8.32) | 5.44 b | (3.33) | 0.73 c | (6.67) | 1.11 d | (8.07) |
| 2507 | nootkatone | 5.81 a | (7.82) | 6.16 a | (2.59) | 4.43 b | (7.56) | 2.86 b | (7.56) | 9.73 a | (1.22) | 11.03 b | (8.13) | 6.86 c | (0.78) | 4.03 d | (10.07) | 19.07 a | (5.70) | 27.75 b | (3.53) | 10.9 c | (9.59) | 13.21 d | (7.25) |
| 2083 | elemol | 3.93 a | (9.47) | 3.47 a | (9.38) | 0.81 a | (3.51) | 0.62 c | (4.98) | 1.82 a | (8.15) | 1.81 a | (13.48) | 1.81 a | (7.63) | 1.29 b | (7.63) | 1.3 a | (10.14) | 0.88 b | (8.13) | 1.65 c | (7.76) | 0.51 d | (0.77) |
| 2121 | γ-eudesmol | 1.12 a | (12.91) | 1.17 a | (3.55) | 0.25 b | (14.88) | 0.78 c | (7.52) | 0.67 a | (9.38) | 0.54 b | (6.67) | 0.51 b | (13.26) | 0.33 c | (13.26) | 0.21 a | (6.73) | 0.31 b | (0.01) | 0.32 b | (8.32) | 0.32 b | (4.07) |
| 2183 | δ-eudesmol | 2.15 a | (1.40) | 2.21 a | (9.38) | 1.17 b | (9.38) | 1.27 b | (2.28) | 5.05 a | (10.05) | 9.09 b | (7.88) | 5.09 a | (6.67) | 3.83 c | (6.67) | 7.81 a | (1.75) | 9.51 b | (2.77) | 4.68 c | (13.26) | 7.57 a | (7.16) |
| 2348 | (E)-farnesol | 1.33 a | (7.63) | 1.93 b | (3.63) | 1.4 a | (8.63) | 1.03 c | (8.07) | 1.58 a | (12.55) | 1.24 ab | (4.85) | 1.08 b | (0.01) | 0.68 c | (0.01) | 1.04 a | (7.52) | 1.62 b | (7.31) | 0.97 a | (12.49) | 1.02 a | (6.86) |
| Total | 76.57 | 86.5 | 51.49 | 31.25 | 55.09 | 66.41 | 49.61 | 41.04 | 64.22 | 88.66 | 28.3 | 42.3 | |||||||||||||
| Terpene oxide | |||||||||||||||||||||||||
| 1428 | (Z)-linalool oxide | 0.11 a | (7.83) | 0.21 b | (6.07) | 0.19 b | (4.47) | traces | 0.17 a | (8.44) | 0.44 b | (8.63) | 0.78 c | (5.14) | 0.51 b | (6.36) | 0.07 a | (10.88) | 0.60 b | (7.75) | 0.57 b | (3.40) | traces | ||
| 1430 | (Z)-limonene-oxide | 0.31 a | (4.98) | 0.64 b | (3.82) | 0.74 c | (0.77) | traces | 0.11 a | (6.73) | 0.79 b | (2.70) | 0.91 c | (7.63) | 0.42 c | (7.04) | 0.09 a | (8.32) | 0.32 b | (6.86) | 0.41 b | (5.82) | 0.20 c | (7.91) | |
| 1453 | (E)-linalool oxide | 0.16 a | (1.40) | 0.65 b | (6.87) | 1.24 c | (2.77) | traces | 0.25 a | (22.63) | 0.29 ab | (15.48) | 0.31 b | (6.96) | 0.01 c | (0.00) | 0.10 a | (14.14) | 0.27 b | (8.63) | 0.67 c | (5.08) | 0.18 ab | (6.82) | |
| Total | 0.58 | 1.50 | 2.17 | 0.03 | 0.53 | 1.52 | 2.00 | 0.94 | 0.26 | 1.19 | 1.65 | 0.39 | |||||||||||||
| Terpenoids alcohols | |||||||||||||||||||||||||
| 1541 | linalool | 66.79 a | (0.88) | 79.79 b | (7.86) | 81.02 b | (6.33) | 48.74 c | (2.24) | 32.52 a | (7.44) | 35.17 a | (14.76) | 45.12 b | (1.53) | 18.47 c | (6.90) | 63.90 a | (6.67) | 108.33 b | (3.24) | 80.96 | (1.36) | 24.52 | (6.99) |
| 1585 | α-terpineol | 32.08 a | (11.55) | 25.01 b | (7.33) | 7.81 b | (7.25) | 7.78 b | (7.44) | 17.61 a | (8.71) | 20.42 b | (7.91) | 7.61 c | (6.86) | 12.01 d | (6.86) | 34.72 a | (12.91) | 29.19 b | (7.52) | 7.00 | (7.99) | 5.86 | (1.13) |
| 1605 | p-menthadienol (I) | 7.35 a | (8.07) | 6.36 b | (5.14) | 13.13 b | (12.91) | 5.19 c | (4.98) | 5.62 a | (11.55) | 5.71 a | (7.75) | 7.76 c | (11.55) | 4.45 d | (7.63) | 8.26 a | (6.09) | 9.76 b | (8.82) | 11.41 | (4.02) | 2.37 | (10.29) |
| 1611 | p-menth-2-en-1-ol | 0.33 a | (14.98) | 0.35 a | (8.15) | 0.21 b | (13.64) | 0.69 c | (11.78) | 0.47 a | (7.88) | 0.37 b | (8.44) | 0.36 b | (4.98) | 0.37 b | (4.98) | 0.25 a | (7.82) | 0.36 b | (7.63) | 0.27 a | (8.57) | 0.09 | (8.32) |
| 1646 | p-menthadienol (II) | 8.94 a | (5.47) | 7.12 b | (7.63) | 7.70 b | (1.40) | 3.54 c | (12.97) | 4.90 a | (7.63) | 4.97 a | (1.16) | 4.12 b | (2.63) | 3.43 c | (8.44) | 6.08 a | (7.88) | 5.90 a | (9.68) | 5.62 ab | (7.63) | 5.19 b | (11.91) |
| 1667 | β-citronellol | 9.61 a | (2.52) | 8.66 b | (3.84) | 12.26 b | (7.44) | 7.64 c | (2.52) | 8.37 a | (0.75) | 8.26 a | (7.82) | 7.85 b | (0.75) | 6.41 c | (9.38) | 2.31 a | (7.56) | 2.77 a | (6.82) | 1.90 b | (9.85) | 5.13 c | (13.38) |
| 1786 | nerol | 14.48 a | (5.81) | 15.60 a | (8.63) | 10.26 b | (4.90) | 12.58 c | (7.63) | 7.46 a | (5.60) | 7.53 a | (7.04) | 7.99 b | (8.60) | 2.20 c | (13.45) | 5.78 a | (13.15) | 5.72 a | (4.07) | 1.38 b | (5.05) | 0.40 c | (7.31) |
| 1838 | geraniol | 14.46 a | (13.24) | 17.84 b | (7.56) | 7.13 b | (8.31) | 0.03 c | (0.00) | 8.97 a | (10.03) | 8.99 a | (7.52) | 5.88 b | (10.03) | 3.39 c | (15.98) | 8.60 a | (9.51) | 8.25 a | (13.26) | 1.46 b | (3.78) | 0.65 c | (5.70) |
| 1834 | (Z)-carveol | 2.28 a | (10.54) | 2.51 a | (4.13) | 2.42 a | (12.63) | 0.03 c | (0.00) | 2.77 a | (3.02) | 4.77 b | (1.94) | 1.53 c | (2.75) | 1.64 c | (7.56) | 1.10 a | (3.33) | 2.05 b | (3.85) | 1.70 c | (1.05) | 0.91 d | (1.91) |
| 1927 | limonyl alcohol | 0.73 a | (8.15) | 0.75 a | (8.07) | 0.59 b | (8.07) | 0.61 b | (7.63) | 0.58 a | (0.00) | 0.82 b | (2.25) | 0.62 a | (3.45) | 0.37 c | (6.99) | 0.21 a | (5.15) | 0.38 b | (4.67) | 0.20 a | (3.05) | 0.12 c | (6.86) |
| 1963 | p-mentha-dien-9-ol | 1.32 a | (9.51) | 1.73 ab | (9.31) | 1.98 b | (6.99) | 1.25 b | (8.63) | 3.58 a | (3.43) | 3.71 a | (6.50) | 2.64 b | (5.43) | 2.36 b | (5.82) | 0.63 a | (5.05) | 1.09 b | (5.14) | 0.61 a | (13.73) | 0.40 c | (7.52) |
| 1996 | perillyl alcohol | 2.04 a | (7.18) | 2.14 a | (0.03) | 2.14 a | (14.74) | 0.81 c | (6.86) | 1.34 a | (2.42) | 2.34 b | (7.52) | 0.79 c | (1.38) | 0.45 d | (9.51) | 0.49 a | (9.59) | 2.76 b | (8.44) | 0.70 c | (2.37) | 0.30 d | (2.87) |
| 2140 | eugenol | 0.39 a | (8.15) | 0.52 b | (3.61) | 0.38 a | (10.05) | 0.16 c | (8.15) | 1.03 a | (3.85) | 1.75 b | (7.52) | 0.98 a | (3.85) | 0.07 c | (5.70) | 0.27 a | (7.31) | 0.34 b | (7.12) | 0.25 a | (7.63) | 0.10 c | (12.97) |
| Total | 160.2 | 168.41 | 147.09 | 88.85 | 95.42 | 104.02 | 93.45 | 55.62 | 132.82 | 176.4 | 113.48 | 46.04 | |||||||||||||
| Monoterpenoid aldehydes | |||||||||||||||||||||||||
| 1468 | citronellal | 3.58 a | (6.33) | 3.99 a | (10.40) | 2.57 b | (7.76) | 0.00 c | 1.14 a | (5.82) | 1.87 b | (4.07) | 1.70 c | (0.71) | 0.00 d | 2.81 a | (0.60) | 3.19 b | (3.35) | 0.99 c | (8.82) | 0.00 d | |||
| 1664 | neral | 3.66 a | (4.95) | 2.88 b | (2.97) | 4.74 c | (1.26) | 7.15 d | (6.73) | 1.33 a | (3.30) | 2.84 b | (6.90) | 3.37 c | (7.45) | 4.11 d | (10.14) | 2.20 a | (2.16) | 4.29 b | (2.67) | 5.95 c | (9.51) | 9.94 d | (10.29) |
| 1712 | geranial | 5.61 a | (1.55) | 4.66 b | (6.73) | 3.74 c | (6.87) | 2.26 d | (5.82) | 3.19 a | (5.99) | 2.09 b | (7.63) | 1.37 c | (9.33) | 1.56 c | (7.63) | 3.60 a | (14.24) | 4.19 b | (11.41) | 7.83 c | (19.37) | 5.69 d | (0.02) |
| Total | 12.85 | 11.53 | 11.05 | 9.41 | 5.66 | 6.8 | 6.44 | 5.87 | 8.61 | 11.67 | 14.77 | 15.63 | |||||||||||||
| Chain aldehydes | |||||||||||||||||||||||||
| 1284 | octanal | 12.04 a | (6.73) | 9.98 b | (1.51) | 5.08 | (7.16) | 3.39 | (5.97) | 6.98 a | (8.38) | 7.17 a | (17.05) | 5.84 c | (7.31) | 2.77 d | (9.94) | 9.57 a | (14.76) | 8.70 b | (1.00) | 7.04 c | (2.00) | 2.33 d | |
| 1386 | nonanal | 2.58 a | (8.13) | 1.63 b | (6.09) | 1.52 b | (13.26) | 0.73 c | (7.56) | 2.00 a | (1.01) | 1.65 b | (3.19) | 1.88 ab | (4.86) | 1.15 c | (2.42) | 2.01 a | (7.63) | 2.10 a | (3.61) | 2.54 b | (2.16) | 0.05 c | |
| 1490 | decanal | 13.91 a | (7.31) | 12.22 b | (4.14) | 11.00 c | (6.09) | 7.00 d | (8.32) | 11.52 a | (3.31) | 11.00 a | (5.08) | 5.86 b | (1.02) | 3.86 c | (1.55) | 4.76 a | (7.63) | 3.44 b | (7.56) | 3.21 b | (5.98) | 0.34 c | |
| Total | 27.83 | 23.93 | 18.1 | 11.12 | 20.5 | 20.42 | 13.58 | 7.78 | 16.34 | 14.24 | 12.49 | 2.72 | |||||||||||||
| Terpene hydrocarbons | |||||||||||||||||||||||||
| 1018 | α- pinene | 13.49 a | (2.77) | 13.58 a | (1.48) | 21.97 b | (4.98) | 8.48 c | (8.03) | 11.12 a | (7.75) | 19.76 b | (3.31) | 21.85 c | (0.98) | 9.50 d | (0.98) | 17.57 a | (4.60) | 17.85 a | (3.05) | 11.58 c | (3.00) | 10.21 d | (10.81) |
| 1104 | β- pinene | 5.63 a | (4.52) | 6.36 b | (5.79) | 7.51 c | (2.76) | 5.20 d | (11.55) | 4.60 a | (8.13) | 5.80 b | (7.91) | 7.43 c | (7.18) | 2.00 d | (8.13) | 11.34 a | (7.56) | 9.64 b | (7.82) | 13.34 c | (11.22) | 1.61 d | (7.76) |
| 1119 | sabinene | 7.65 a | (13.34) | 9.47 b | (2.17) | 13.94 c | (8.32) | 4.84 d | (4.98) | 5.90 a | (10.07) | 7.14 b | (2.87) | 10.53 c | (7.99) | 3.10 d | (2.87) | 9.56 a | (3.97) | 11.84 b | (4.13) | 14.25 c | (6.73) | 3.69 d | (8.63) |
| 1209 | limonene | 1687.15 a | (4.98) | 1637.25 a | (1.59) | 2055.82 b | (7.31) | 986.05 c | (11.78) | 1677.04 | a (0.79) | 1700.36 b | (0.65) | 2005.28 c | (0.44) | 852.33 d | (7.83) | 2107.74 a | (3.65) | 2190.26 b | (0.72) | 2424.57 c | (8.32) | 925.92 d | (7.31) |
| 1237 | (Z)-b-ocimene | 0.31 a | (11.78) | 0.48 b | (7.16) | 0.75 c | (1.54) | 0.15 d | (3.61) | 0.23 a | (7.99) | 0.32 b | (0.77) | 0.43 c | (12.91) | 0.14 d | (0.77) | 0.45 a | (10.40) | 0.41 a | (6.90) | 0.59 b | (7.63) | 0.00 c | |
| 1254 | γ-terpinene | 3.19 a | (5.70) | 3.46 b | (5.95) | 3.77 c | (3.26) | 2.21 d | (1.40) | 2.08 a | (9.45) | 2.34 a | (8.47) | 3.37 c | (10.29) | 2.21 d | (7.45) | 3.14 a | (0.71) | 3.99 b | (1.98) | 2.72 c | (7.52) | 0.78 d | (10.92) |
| 1256 | (E) b-ocimene | 1.73 a | (3.33) | 2.28 b | (14.80) | 3.26 c | (1.40) | 1.59 d | (9.82) | 1.39 a | (8.71) | 1.69 a | (9.82) | 3.23 c | (7.12) | 0.76 d | (2.78) | 0.60 a | (1.94) | 0.49 b | (6.90) | 0.64 a | (0.26) | 0.41 b | (5.69) |
| 1269 | p-cymene | 0.73 a | (4.11) | 0.86b | (4.79) | 0.91 b | (3.51) | 0.69 c | (12.97) | 0.42 a | (9.04) | 0.46 a | (11.17) | 0.46 a | (9.61) | 0.20 d | (2.77) | 0.38 a | (3.31) | 0.40 a | (3.61) | 1.09 b | (7.25) | 0.25 c | (6.86) |
| 1289 | α-terpinolene | 2.55 a | (8.38) | 2.47 a | (10.14) | 3.01 b | (5.14) | 1.21 c | (12.32) | 2.50 a | (6.93) | 2.36 a | (8.22) | 3.28 b | (8.32) | 1.42 c | (8.32) | 3.83 a | (7.99) | 4.42 b | (7.44) | 3.15 c | (9.07) | 0.59 d | (8.62) |
| 1368 | alloocimene | 0.11 a | (8.13) | 0.11 a | (1.75) | 0.20 b | (17.91) | 0.10 c | (0.98) | 0.17 a | (3.55) | 0.15 a | (7.41) | 0.18 a | (14.93) | 0.07 d | (2.70) | 0.09 a | (8.47) | 0.12 a | (7.82) | 0.23 c | (3.13) | 0.08 a | (11.55) |
| 1427 | p-cymenene | 0.31 a | (7.99) | 0.66 | (6.86) | 1.68 b | (2.87) | 0.75 c | (7.41) | 0.23 a | (7.44) | 0.10 b | (7.44) | 0.62 c | (9.05) | 0.00 d | 0.35 a | (7.88) | 1.35 b | (6.40) | 1.48 b | (5.70) | 0.19 c | (3.61) | |
| 1521 | β-cubenene | 0.35 a | (7.52) | 0.69 b | (6.73) | 0.90 c | (7.16) | 0.42 d | (7.31) | 1.23 a | (3.33) | 0.54 b | (3.33) | 0.83 c | (7.63) | 1.28 a | (7.18) | 0.44 a | (13.26) | 0.41 a | (6.09) | 1.20 c | (6.93) | 0.28 d | (8.15) |
| 1578 | transCaryophyllene | 2.14 a | (6.86) | 2.96 b | (5.82) | 6.62 b | (2.59) | 1.77 c | (6.86) | 4.09 a | (11.62) | 4.45 ab | (4.60) | 4.77 b | (1.36) | 2.01 c | (6.09) | 2.75 a | (8.13) | 3.59 b | (1.57) | 7.50 c | (10.89) | 2.14 d | (9.38) |
| 1703 | β-selinene | 2.52 a | (0.36) | 3.30 b | (1.49) | 4.43 c | (7.21) | 0.30 d | (8.15) | 4.58 a | (10.72) | 4.13 a | (11.69) | 5.81 b | (6.44) | 2.39 c | (14.76) | 2.30 a | (3.26) | 2.90 b | (7.52) | 4.67 c | (4.65) | 1.62 d | (7.88) |
| Total | 1727.86 | 1683.49 | 2124.68 | 1013.76 | 1715.58 | 1749.1 | 2068.09 | 877.72 | 2190.64 | 2236.98 | 2487.17 | 947.84 | |||||||||||||
| Terpene Esters | |||||||||||||||||||||||||
| 1546 | linalyl acetate | 0.82 a | (6.86) | 0.64 b | (0.22) | 0.41 c | (8.32) | 0.00 d | 0.09 a | (12.91) | 0.11 a | (10.00) | 0.01 b | (1.00) | 0.00 c | 1.13 a | (13.65) | 0.89 b | (5.06) | 0.41 c | (4.98) | 0.29 d | (1.01) | ||
| 1570 | bornyl acetate | 0.48 a | (8.63) | 0.26 b | (6.99) | 0.24 b | (5.70) | 0.00 c | 0.38 a | (1.09) | 0.36 b | (6.53) | 0.34 a | (1.02) | 0.12 b | (14.76) | 0.19 a | (1.82) | 0.25 b | (1.00) | 0.01 c | (0.00) | 0.01 d | (0.00) | |
| 1644 | citronelly acetate | 0.23 a | (6.86) | 0.20 a | (10.05) | 0.12 b | (3.61) | 0.11 b | (9.82) | 0.16 a | (1.40) | 0.14 b | (1.40) | 0.00 b | 0.00 b | 1.41 a | (5.70) | 1.33 a | (6.99) | 1.41 a | (8.44) | 0.68 b | (2.15) | ||
| 1673 | terpinyl acetate | 3.80 a | (13.65) | 3.49 a | (13.26) | 1.08 b | (10.14) | 0.82 c | (12.97) | 1.36 a | (0.00) | 1.30 a | (0.00) | 1.16 b | (7.12) | 0.64 c | (6.73) | 3.22 a | (5.70) | 2.51 b | (2.63) | 0.45 c | (8.47) | 0.57 d | (8.13) |
| 1711 | geranyl acetate | 0.51 a | (4.30) | 0.49 a | (6.86) | 0.30 b | (10.14) | 0.17 c | (7.63) | 1.38 a | (7.42) | 0.49 b | (5.70) | 0.37 c | (8.71) | 0.27 d | (11.92) | 0.53 a | (10.07) | 0.55 a | (6.86) | 0.51 a | (7.75) | 0.26 b | (7.82) |
| 1742 | neryl acetate | 0.72 a | (12.55) | 0.77 a | (3.61) | 0.39 b | (3.64) | 0.23 c | (8.15) | 0.68 a | (2.46) | 0.66 a | (2.68) | 0.50 b | (0.00) | 0.32 c | (10.68) | 1.04 a | (3.92) | 1.09 a | (1.82) | 0.80 b | (2.90) | 0.34 d | (5.09) |
| Total | 6.56 | 5.72 | 2.54 | 1.39 | 4.05 | 3.08 | 2.39 | 1.36 | 7.72 | 6.38 | 3.59 | 2.15 | |||||||||||||
| C6 Alcohols | |||||||||||||||||||||||||
| 1350 | 1-hexanol | 10.21 a | (12.97) | 9.83 a | (0.31) | 1.04 b | (8.13) | 0.00 c | 2.76 a | (1.01) | 2.01 b | (1.36) | 0.76 c | (36.35) | 0.00 d | 1.73 a | (6.86) | 1.69 a | (9.68) | 0.67 b | (12.91) | 0.32 c | (8.63) | ||
| 1381 | (Z)-3-hexen-1-ol | 3.55 a | (0.98) | 3.39 a | (2.08) | 0.26 b | (10.07) | 0.00 c | 1.30 a | (8.19) | 1.07 a | (5.98) | 0.19 b | (0.00) | 0.00 c | 0.58 a | (8.71) | 0.52 a | (8.63) | 0.14 b | (4.98) | 0.00 c | |||
| Total | 13.76 | 13.22 | 1.30 | 0,00 | 4.06 | 3.08 | 0.95 | 0.00 | 2.31 | 2.11 | 0.81 | 0.33 | |||||||||||||
KI: Kovats index; a, b, c, d: Different letters in the same row denote significant difference according to the Student-Newman-Keuls test (p < 0.05).