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. 2021 Sep 30;93(40):13548–13554. doi: 10.1021/acs.analchem.1c02491

Table 2. HG-MC-ICPMS Operating Parameters.

MC-ICPMS parameters  
RF power 1300 W
coolant flow (Ar) 13 L/min
auxiliary flow (Ar) 1.15 L/min
nebulizer gas flow (Ar) 0.69 L/min
interface cones nickel
   
measurement parameters  
resolution mode ∼300
cup configuration H4: 74Ge; H2: 73Ge; Ax: 72Ge; L4: 70Ge
integration time 2.5 s
measurement mode time-resolved analysis
replicates ≥50
   
hydride generation  
“acid” reagent 0.1 M sodium acetate buffer
reducing agent NaBH4 (1%) mixed with NaOH (0.01 M)
reagents and sample flow rate 0.83 mL/min
sample gas rotameter position 10 mm
additional gas flow rate 0.7 L/min