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Computed stationary points of the activation mechanism for the studied precatalyst [Pd]‐Cl‐1−4 series ([Pd]‐Cl‐4, R1=R2=H; [Pd]‐Cl‐2, R1=H, R2=Me; [Pd]‐Cl‐3, R1=R2=Me; [Pd]‐Cl‐4, R1=H, R2=Ph). Relative Gibbs energies are given in kcal/mol. Figure extracted from Ref. [94].
