Table 3.
Zero force elementary rate constants and equilibrium parameters for different stereoisomers. Parameters calculated from kinetic measurements. Error corresponds to one standard deviation.
|
|
k 1(0) [×105 M−1 s−1] |
Δx 1 [nm] |
k −1(0) [×10−3 s−1] |
Δx −1 [nm] |
k 2(0) [×10−3 s−1] |
Δx 2 [nm] |
K d 0 [nM] |
Δx eq [nm] |
n |
|---|---|---|---|---|---|---|---|---|---|
|
Λ,Λ‐1 |
6.1±2.4 |
0.23±0.01 |
2.6±0.3 |
0.05±0.01 |
4.9±0.8 |
0.12±0.02 |
7.6±1.5 |
0.25±0.02 |
2.1±0.2 |
|
Λ,Δ‐1 |
10.5±1.2 |
0.22±0.01 |
9.4±0.4 |
−0.02±0.01 |
10.3±1.5 |
0.07±0.02 |
10.2±1.0 |
0.25±0.01 |
2.2±0.2 |
|
Δ,Δ‐1 |
11.6±1.5 |
0.20±0.01 |
5.3±0.3 |
0.05±0.01 |
5.6±0.6 |
0.08±0.01 |
8.9±0.9 |
0.24±0.01 |
2.2±0.2 |