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. 2021 Aug 19;14(18):3636–3664. doi: 10.1002/cssc.202101272

Scheme 2.

Scheme 2

Fossil carbon can be converted to oxalic acid via four pathways: (a) naphtha can be converted to ethylene glycol (via ethylene), which can be oxidized to oxalic acid; (b) propylene is obtained from naphtha cracking and can be converted to oxalic acid; (c) fossil carbon is converted to CO in a gasification process, which can be converted to oxalic acid via the dialkyl oxalate process; and alternatively (d) CO can be converted to formate, which is turned into oxalic acid using formate coupling followed by an acidification step.