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. 2021 Aug 26;60(40):21784–21788. doi: 10.1002/anie.202108370

Scheme 1.

Scheme 1

a–d) Selected examples of reversible [2+2] cycloaddition reactions of multiply bonded compounds (isoelectronic to gallaphosphene 1) containing heavier main group elements. e) [2+2] Cycloaddition reactions of gallaphosphene 1 with heteroallenes.