Table 1. Branching Fractions (BF) (%) of All Possible Reaction Channels for the Reaction N(2D) + CH3CCH from Addition Pathways and Insertion Pathways at Total Energy of 31.0 kJ/mol (See Text).
| reaction channel | products | addition (MIN1) BF (%) | insertion (MIN5) BF (%) |
|---|---|---|---|
| a | CH3CH + CN | 0.0% | |
| b | CCNH + CH3 | 0.1% | |
| c | c-H2CC(NH)C + H | 0.4% | |
| d | CH3CCN + H | 0.9% | |
| e | HCCN + CH3 | 1.5% | |
| f | c-CH3C(N)C + H | 6.4% | |
| g | c-C(N)CH + CH3 | 56.9% | |
| h | CH2NH + CCH | 94.7% | |
| i | c-CH2C(N)CH + H | 7.5% | |
| j | CH2CCNH + H | 3.8% | |
| k | CHCCHNH + H | 5.3% | |
| l | C2H4 + CN | 1.2% | |
| m | C2H3 + HCN | 0.02% | |
| n | CH2CHCN + H | 21.1% |