Table 2. Global Branching Fractions (%) for All Possible Reaction Channels for the Reaction N(2D) + CH3CCH at Different Values of Total Energy (See Text).
| reaction channel | products | 0.8 kJ/mol | 1.5 kJ/mol | 2.5 kJ/mol | 31.0 kJ/mol |
|---|---|---|---|---|---|
| a | CH3CH + CN | 0.0% | 0.0% | 0.0% | 0.0% |
| b | CCNH + CH3 | 0.02% | 0.02% | 0.02% | 0.04% |
| c | c-H2CC(NH)C + H | 0.1% | 0.1% | 0.1% | 0.2% |
| d | CH3CCN + H | 0.5% | 0.5% | 0.5% | 0.5% |
| e | HCCN + CH3 | 0.9% | 0.9% | 0.9% | 0.9% |
| f | c-CH3C(N)C + H | 2.9% | 3.0% | 3.1% | 3.6% |
| g | c-C(N)CH + CH3 | 27.7% | 28.1% | 29.0% | 32.0% |
| h | CH2NH + CCH | 41.1% | 41.1% | 41.2% | 41.4% |
| i | c-CH2C(N)CH + H | 4.2% | 4.2% | 4.2% | 4.2% |
| j | CH2CCNH + H | 2.7% | 2.7% | 2.6% | 2.2% |
| k | CHCCHNH + H | 2.6% | 2.5% | 2.5% | 2.3% |
| l | C2H4 + CN | 0.9% | 0.9% | 0.8% | 0.7% |
| m | C2H3 + HCN | 0.01% | 0.01% | 0.01% | 0.01% |
| n | CH2CHCN + H | 16.26% | 15.85% | 14.99% | 11.9% |