Table 3.

Performance of McGlc and PcGlc in optimized transglycosylation reactions at low and high conversions with dissolved 2 and 2-phenylethanol^a

	TOFc		Productivityd		STYe
Xb	0.2	0.7	0.2	0.7	0.2	0.7
McGlc	13	6.9	1240	640	86	44
PcGlc	8.9	2.9	901	292	57	19

^aUsing a substrate to enzyme (S/E) ratio of 67,000 mol mol^–1. Reaction conditions: 35 °C, 25% (v/v) DMSO, 100 mM initial concentration of 2; 200 or 397 mM of 2-phenylethanol for McGlc or PcGlc-based reactions, respectively. The quantification of quercetin and compound 6 enabled the determination of the total (i.e., hydrolysis and transglycosylation) and the transglycosylation-specific conversion, respectively

^bX: conversion of glycosyl donor 2

^cTurnover frequency: 10⁴ mol of 6·(mole of catalyst·h)^–1

^dCatalyst productivity: g of 6·(g catalyst·h)^–1

^eSpace–time yield: g of 6·(L·h)^–1