The TTFTC˙⁺ population (i.e., spin/TTFTC ligand), electronic and optical band gaps, electrical conductivity, and activation energy of MOFs.

	Na-MOF 1-ox	K-MOF		Rb-MOF		Cs-MOF 4
		2	2-ox	3	3-ox
% TTFTC˙+ population	23 (0.23)	16 (0.16)	25 (0.25)	0.5 (0.005)	10 (0.1)	0.3 (0.003)
E opt (eV)—expt.	1.33	1.99	1.35	2.12	1.37	2.11
σ avg (S cm−1, 293 K)	3.4 (±0.11) × 10−5	1.7 (±0.3) × 10−5	6.3 (±0.6) × 10−5	1.5 (±0.2) × 10−5	4.1 (±0.4) × 10−5	1.3 (±0.3) × 10−7
σ max (S cm−1, 293 K)	3.6 × 10−5	2.1 × 10−5	6.6 × 10−5	1.7 × 10−5	4.7 × 10−5	1.75 × 10−7
E a (eV)	0.06	0.18	0.16	0.19	0.19	—