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Fig. 1. Phase transition behaviour of M+·(1)·X− salts and the formation of the Colh phase. (a) DSC profiles of K+·(1)·SCN− (red) and K+·(1)·I− (blue). (b) Temperature ranges of the solid phase (red) and Colh phase (blue). POM images of the Colh phase of (c) K+·(1)·I− at 483 K and (d) K+·(1)·SCN− at 473 K.